GC-MS exploration of photochemically generated species of Os, W and Ru from reductive and oxidative media

• DOI: 10.1039/d1ja00448d
• Publication Date: 2022-02-18T09:01:00Z
• Authors: Enea Pagliano; Jaromír Vyhnanovský; Stanislav Musil; Richard M. de Oli...; Sándor T. Forczek; Ralph E. Sturgeon
• Keywords: vapor generation; optical-emission; fluorescence spectrometric determination; sensitive determination; PVG mechanisms; osmium tetroxide; mass-spectrometry; photochemical vapor generation; 01 natural sciences; 0104 chemical sciences; tungsten hexacarbonyl; GC-MS; ruthenium

GC-MS identification of W(CO)6 and OsO4 confirms these products of photochemical vapor generation from W(vi) and Os(iv) in reductive and oxidative media, respectively.