Room-temperature phosphorescence of a supercooled liquid: kinetic stabilisation by desymmetrisation

Supercooling Conformational isomerism
DOI: 10.1039/d1sc03800a Publication Date: 2021-09-10T12:41:02Z
ABSTRACT
Metal-free, single-component, unsymmetrical 1,2-diketone exhibits liquefaction-induced room-temperature phosphorescence. Desymmetrisation provides the supercooled liquid with notable kinetic stability and phase-dependent phosphorescence properties.
SUPPLEMENTAL MATERIAL
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