Experimental and theoretical study of the mechanism and rate constants of the sequential 5-exo-trig spirocyclization involving vinyl, aryl and N-alkoxyaminyl radicals

• DOI: 10.1039/d2ob00387b
• Publication Date: 2022-04-21T17:02:03Z
• Authors: Carlos A. Bejarano; John E. Díaz; Andrés Cifuentes-...; Lina V. López; Luz M. Jaramillo-...; Cristian Buendia-...; Vaneza Paola Lore...; Sol M. Mejía; Alix E. Loaiza
• Keywords: Free Radicals; Molecular Structure; 5-exo-trig cyclization; Models, Theoretical; 01 natural sciences; 0104 chemical sciences; Kinetics; Oximes; https://purl.org/becyt/ford/1.4; Density functional theory DFT; Radical reaction; https://purl.org/becyt/ford/1; Ethers

The mechanism and kinetic constants of the cascade cyclization involving vinyl, aryl and N-alkoxyaminyl radicals for the formation of 1-azaspiro[4.4]nonanes.