Visible-light driven photocatalytic CO2reduction promoted by organic photosensitizers and a Mn(i) catalyst

• DOI: 10.1039/d3se00546a
• Publication Date: 2023-06-27T13:19:39Z
• Authors: Elena Bassan; Rei Inoue; David Fabry; Francesco Calogero; Simone Potenti; Andrea Gualandi; Pier Giorgio Cozzi; Kei Kamogawa; Paola Ceroni; Yusuke Tamaki; Osamu Ishitani

Organic chromophores displaying TADF emission were coupled to a Mn(i)-complex as the catalyst and investigated as photosensitizers for CO2reduction. Upon 470 nm LED excitation, TONCO+HCOOH> 650 and aΦCO+HCOOH= 22.8% were obtained.