Tetranuclear NiII-Mannich base complex with oxygenase, water splitting and ferromagnetic and antiferromagnetic coupling properties

• DOI: 10.1039/d4dt01425a
• Publication Date: 2024-07-15T14:28:05Z
• Authors: Arka Patra; Avijit Das; Abhimanyu Sarkar; Carlos J. Gómez-G...; Chittaranjan Sinha
• Keywords: 01 natural sciences; 0104 chemical sciences

The rhombic-tetranuclear NiII [Ni4(L)2(μ1,1Cl)2(H2O)4]2+ (1) complex with two types of Ni(ii) pairs shows ferro and antiferromagnetic exchange and catalytic oxidase activities of catechol and o-aminophenol. The complex shows OER and HER activities.