Variation in the zero-point energy difference via electrostatic interactions in Co(ii)-Cltpy-based spin-crossover molecular materials

• DOI: 10.1039/d4tc02203c
• Publication Date: 2024-10-24T16:21:17Z
• Authors: Mousumi Dutta; Ajana Dutta; Prabir Ghosh; Shubhankar Maiti; Laurentiu Stoleriu; Cristian Enachescu; Pradip Chakraborty
• Keywords: Spin Crossover; Zero-point energy; Variation (astronomy); Zero (linguistics)

Newly synthesized Co(II)-Cltpy-based spin-crossover molecular materials involving ClO4-, BF4-, PF6-, and CF3SO3- are systematically investigated by emphasizing the structure-property interplay. The multi-facet character of ligand, 4′-Chloro-2,2′:6′,2′′-terpyridine (Cltpy) makes the...