Isotopic dependence of the predissociations of the E1Π state of CO

• DOI: 10.1063/1.4918910
• Publication Date: 2015-04-27T17:00:41Z
• Authors: H. Lefebvre-Brion; M. Majumder
• Keywords: 0103 physical sciences; 01 natural sciences

The predissociations of the E(1)Π state CO are again studied. They include both background predissociation attributed to continuum A(1)Π and accidental due k(3)Π state. calculated using a coupled equations method. three components k introduced. These studied for different isotopologues shown decrease with increasing reduced mass, in agreement experimental results Ubachs et al. [J. Chem. Phys. 113, 547 (2000)].