Enhancement and maximum in the isobaric specific-heat capacity measurements of deeply supercooled water using ultrafast calorimetry

• DOI: 10.1073/pnas.2018379118
• Publication Date: 2021-02-01T23:36:58Z
• Authors: Harshad Pathak; Alexander Späh; Niloofar Esmaeild...; Jonas A. Sellberg; Kyung Hwan Kim; Fivos Perakis; Katrin Amann-Winkel; Marjorie Ladd-Parada; Jayanath Koliyadu; Thomas J. Lane; Cheolhee Yang; Henrik Till Lemke; Alexander Roland ...; Philip J. M. Johnson; Yunpei Deng; Serhane Zerdane; Roman Mankowsky; Paul Beaud; Anders Nilsson
• Keywords: Fysikalisk kemi; 0303 health sciences; Supercooled water; ICE; ENTROPY; liquid-liquid critical point; REGIONS; Physical Chemistry; 7. Clean energy; COMPRESSIBILITY; 03 medical and health sciences; TEMPERATURE-DEPENDENCE; Specific-heat capacity; Fragile-to-strong transition; Liquid-liquid critical point; 13. Climate action; fragile-to-strong transition; Physical Sciences; specific-heat capacity; LIQUID TRANSITION; BEHAVIOR; supercooled water

Significance The importance of molecular understanding of the structure, dynamics. and properties of liquid water is recognized in many scientific disciplines. Here, we study experimentally the structure and thermodynamics of bulk liquid water as it is supercooled by evaporation down to ∼228 K. The unique aspect of this work is the use of ultrafast calorimetry that enables us to determine the specific-heat capacity of water to unprecedentedly low temperatures. The observed maximum of about 218 J/mol/K at 229 K is consistent with the liquid–liquid critical point model and supports a proposed fragile-to-strong transition at ∼220 K to explain the steep decrease in the estimated self-diffusion coefficient below 235 K.