Phonon Dispersions of fcc δ-Plutonium-Gallium by Inelastic X-ray Scattering

• DOI: 10.1126/science.1087179
• Publication Date: 2003-08-21T20:01:54Z
• Authors: Joe Wong; Michael Krisch; Daniel L. Farber; Florent Occelli; Adam J. Schwartz; Tai-C. Chiang; Mark Wall; Carl Boro; Ruqing Xu
• Keywords: 0103 physical sciences; 01 natural sciences

We report an experimental determination of the phonon dispersion curves in a face-centered cubic (fcc) δ-plutonium–0.6 weight % gallium alloy. Several unusual features, including a large elastic anisotropy, a small-shear elastic modulus C′, a Kohn-like anomaly in the T 1 [011] branch, and a pronounced softening of the [111] transverse modes, are found. These features can be related to the phase transitions of plutonium and to strong coupling between the lattice structure and the 5f valence instabilities. Our results also provide a critical test for theoretical treatments of highly correlated 5f electron systems as exemplified by recent dynamical mean field theory calculations for δ-plutonium.