A5085491954- X-ray Diffraction in Crystallography
- Crystallization and Solubility Studies
- Nanoplatforms for cancer theranostics
- Luminescence and Fluorescent Materials
- MXene and MAX Phase Materials
- Photodynamic Therapy Research Studies
- Porphyrin and Phthalocyanine Chemistry
- Advanced Photocatalysis Techniques
- Synthesis and Properties of Aromatic Compounds
- Perovskite Materials and Applications
- Crystallography and molecular interactions
- Photochromic and Fluorescence Chemistry
- Ammonia Synthesis and Nitrogen Reduction
- Innovative Microfluidic and Catalytic Techniques Innovation
- Inorganic Chemistry and Materials
- Hydrogen Storage and Materials
- Boron and Carbon Nanomaterials Research
- Covalent Organic Framework Applications
- 2D Materials and Applications
University of Science and Technology Beijing
2024-2025
East China University of Science and Technology
2021-2024
To gain insights into the coupling of conformational and electronic variables, we exploited steric hindrance to modulate a polycyclic skeleton with bent conformation in S0 state twisted S1 under guidance photoexcited aromaticity reversals. Polycyclic 5,10-dihydrophenazine (DHP) adopted structure but involved bent-to-planar transformation due excited-state 8π-electron central ring. The N,N'-locations 1,4,6,9-sites DHP provided versatile chemical handle for fine-tuning intramolecular...
Simple donor–acceptor (D–A) molecules with large Stokes-shifted and bright near-infrared (NIR) emissions are extremely attractive for the high-resolution three-photon fluorescence (3PF) imaging of deep tissues. Herein, we present a new strategy significantly extending Stokes shifts D–A fluorophores, relying on increasing excited-state structural/electronic relaxation donor moiety. The prototype structure DPCN, containing planar N,N′-diphenyl-dihydrophenazine (DHP) acceptor malononitrile,...
An AIE-active type I photosensitizer DMPpy based on DHP was developed to efficiently generate superoxide anion radical (O 2 − ˙) for overcoming the hypoxic dilemma in solid tumors with NIR emission (∼700 nm), large Stokes shifts (∼270 nm) and mitochondrial targeting ability.
The diketopyrrolopyrrole-based theranostic prodrug (DPP-QS) releases LD-targeted AIE PS (DPP-QE) and drug (chlorambucil) under the cleavage of esterase to achieve precise pyroptosis chemo-photodynamic therapy pancreatic cancer.
Radionuclides, such as strontium (Sr), are hazardous radioactive isotopes commonly found in nuclear waste, posing serious environmental and health risks due to their long half-lives ability bioaccumulate. Inspired by the electronic modification effect, this study theoretically predicts that doping can significantly enhance adsorptive performance of MXenes for radionuclides. Specifically, we employed comprehensive first-principles simulations investigate impact nitrogen (N) on adsorption...
AIE-active type I photosensitizers based on DHP were developed by regulating the donor configuration, in which SMP-CNPY with one methyl modification showed high-performance photodynamic therapy under hypoxia and lipid droplet targeting ability.
The interlayer hydrogen bond-assisted poly(PDI) photocatalyst BU-PDI exhibits the highest oxygen evolution rate of 46.8 μmol h −1 under visible-light irradiation because its huge built-in electric field improves charge separation and migration.