A5044138353- Crystal structures of chemical compounds
- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Organometallic Compounds Synthesis and Characterization
- Metal complexes synthesis and properties
- Crystallography and molecular interactions
- Metal-Organic Frameworks: Synthesis and Applications
- Magnetism in coordination complexes
- Thermal and Kinetic Analysis
- Chemical Thermodynamics and Molecular Structure
- Inorganic and Organometallic Chemistry
- Medical Imaging and Analysis
- Conducting polymers and applications
- Metal-Catalyzed Oxygenation Mechanisms
- Organometallic Complex Synthesis and Catalysis
- Electrochemical Analysis and Applications
- Artificial Intelligence in Healthcare
- Spinal Fractures and Fixation Techniques
- Electrochemical sensors and biosensors
- Scoliosis diagnosis and treatment
Jining University
2007-2023
Qufu Normal University
2010
Jining First People's Hospital
2006
Comparative study.To compare manual and deep learning-based automated measurement of Cobb angle in adolescent idiopathic scoliosis.We proposed a fully framework to measure the AIS patients. Whole-spine images 500 individuals were collected. 200 digital radiographic (DR) labeled manually as training set, remaining 300 used validate by mean absolute error (MAE), Pearson or spearman correlation coefficients, intra/interclass coefficients (ICCs). The relationship between accuracy vertebral...
The asymmetric unit of the title compound, [Sn(C6H5)2(C14H11N3O3)], contains two crystallographically independent molecules that differ predominantly in torsion phenyl rings. In both molecules, SnIV ion is a distored trigonal-bipyramidal geometry. Sn—O distances are range 2.055 (2)–2.143 (2) Å.
The title complex, [Cu(2)(C(13)H(16)N(3)O(3))(C(12)H(8)N(2))(H(2)O)]NO(3), consists of a nitrate ion and binuclear Cu(II) unit in which the oxamide ligand has cis geometry, is fully deprotonated acts bidentate fashion to one atom tetradentate other atom. coordination geometries are distorted square-planar square-pyramidal. In crystal structure, complexes ions connected by classical O-H⋯O non-classical C-H⋯O hydrogen bonds into three-dimensional framework. alkyl chains anion equally disorded...
Using the medical big data mining related technology, model of tumor disease was analyzed and studied. science methods as a guiding method idea, analyzing constructing service based on for oncology diseases, exploring its development strategy; using business process analysis to analyze mapping cancer services; serviceoriented architecture Design methodology build highly flexible, configurable, easily scalable precision platform. By characteristics shortcomings traditional Apriori algorithm,...
Polynuclear complexes are an important class of inorganic functional materials and interest particularly for their applications in molecular magnets. Multidentate chelating ligands play role the design syntheses polynuclear metal clusters. A novel linear tetranuclear Co(II) cluster, namely bis{μ3-(E)-2-[(2-oxidobenzylidene)amino]phenolato}bis{μ2-(E)-2-[(2-oxidobenzylidene)amino]phenolato}bis(1,10-phenanthroline)tetracobalt(II), [Co4(C14H11NO2)4(C12H8N2)2], was prepared under solvothermal...
In the cation of title compound, [CoCl(C(10)H(8)N(2))(2)]ClO(4), Co(II) atom displays a distorted trigonal-bipyramidal coordination geometry. The two pyridine rings in each 2,2'-bipyridine ligand form dihedral angles 10.75 (12) and 4.28 (13)°. crystal packing is stabilized by inter-ionic C-H⋯O hydrogen bonds, C-H⋯π inter-actions aromatic π-π stacking inter-actions, with centroid-centroid distances 3.616 (7) Å.
The title compound, [Sn(CH(3))(2)(C(6)H(3)BrNO(2))(2)], possesses an infinite chain structure owing to the presence of Sn-N bridges between adjacent mol-ecules. SnO(4)NC(2) centre has a distorted penta-gonal-bipyramidal geometry with C atoms in axial positions.
Abstract C 29 H 31 Cl 2 NO 4 Sn, monoclinic, P 1 / n (no. 14), a = 10.638(4) Å, b 17.168(7) c 18.399(5) β 120.573(16)°, V 2893.1(18) Å 3 , Z 4, R gt ( F ) 0.0314, wR ref 0.0875, T 298 K.
The title compound, [Sn(C4H9)2(C6H3BrNO2)2]n, displays an infinite chain structure owing to the presence of Sn—N bridges between adjacent monomer units. Sn centre has a distorted pentagonal–bipyramidal geometry defined by C2NO4 donor set with C atoms occupying axial positions.
Abstract C 34 H 50 N 6 O Sn 2 , triclinic, P <m:math xmlns:m="http://www.w3.org/1998/Math/MathML" overflow="scroll"> <m:mrow> <m:mover accent="true"> <m:mn>1</m:mn> <m:mo>‾</m:mo> </m:mover> </m:mrow> </m:math> $\overline{1}$ a = 12.110(2) Å, b 12.406(2) c 13.744(3) α <m:mn>79.547</m:mn> <m:mo>(</m:mo> <m:mn>2</m:mn> <m:mo>)</m:mo> <m:mo>°</m:mo> $79.547(2){}^{\circ}$ β <m:mn>82.072</m:mn> $82.072(2){}^{\circ}$ γ <m:mn>87.257</m:mn> $87.257(2){}^{\circ}$ V 2010.7(7) Å 3 Z 2, R gt ( F )...
In the title complex, [Sn(CH(3))(2)(C(14)H(11)N(3)O(3))], Sn atom is in a distorted trigonal-bipyramidal coordination, with Sn-O distances of 2.138 (2) and 2.176 Å. The dihedral angles between two chelated benzene rings O-Sn-N group are 71.73 (9) 83.30 (9)°.
The title compound, [Sn(4)(C(8)H(17))(8)O(2)(C(6)H(5)N(2)O(2))(4)], is a tetra-nuclear Sn(IV) complex, built up by inversion symmetry around the central Sn(2)O(2) ring. coordination geometries are distorted SnO(3)C(2) trigonal-bipyramidal and SnO(4)C(2) octa-hedral. three-coordinate μ(3)-oxido bridging O atom in ring attached to three Sn atoms. All non-H atoms, with exception of Sn-bonded octyl groups, lie approximately on non-crystallographic mirror plane.
In the title methanol disolvate complex, [Ni4(C14H16N3O4)2(ClO4)2(C10H8N2)2]·2CH3OH, neutral tetranickel(II) system lies on a centre of inversion. The polyhedron around each Ni(II) atom is square pyramid. separations Ni atoms bridged by oxamide and carboxyl groups are 5.227 (9) 5.268 (6) Å, respectively. crystal structure, two-dimensional supramolecular network structure involving O—H⋯O C—H⋯O hydrogen bonding observed.
In the monomeric title compound, [Sn(C(4)H(9))(2)(C(6)H(5)N(2)O(2))(2)(H(2)O)]·CH(3)OH, Sn atom is seven-coordinate, displaying a distorted penta-gonal bipyramidal SnC(2)N(2)O(3) geometry with two C atoms in axial sites. crystal structure, inter-molecular O-H⋯O hydrogen bonds link complex and solvent mol-ecules into infinite chains.
In the mol-ecule of title compound, [Sn(C(6)H(5))(2)(C(6)H(5)N(2)O(2))(2)], two O and one N atoms from 5-methyl-pyrazine-2-carboxyl-ate ligands C atom a phenyl group form distorted square-planar arrangement in equatorial plane around Sn atom, while octa-hedral coordination is completed by an other axial positions. crystal structure, inter-molecular C-H⋯O hydrogen bonds link mol-ecules into centrosymmetric dimers.