A5059241268- X-ray Diffraction in Crystallography
- Crystallization and Solubility Studies
- Magnetism in coordination complexes
- Metal complexes synthesis and properties
- Lanthanide and Transition Metal Complexes
- Porphyrin and Phthalocyanine Chemistry
- Crystallography and molecular interactions
- Microstructure and mechanical properties
- Synthesis and characterization of novel inorganic/organometallic compounds
- Organometallic Complex Synthesis and Catalysis
- Metal-Catalyzed Oxygenation Mechanisms
- Synthesis and Biological Evaluation
- Metal-Organic Frameworks: Synthesis and Applications
- Electron Spin Resonance Studies
- Photochemistry and Electron Transfer Studies
- Organoboron and organosilicon chemistry
- Oxidative Organic Chemistry Reactions
- Advanced Materials Characterization Techniques
- Electrochemical Analysis and Applications
- Organic and Molecular Conductors Research
- Advanced materials and composites
- Fusion materials and technologies
- Inorganic and Organometallic Chemistry
- Microstructure and Mechanical Properties of Steels
- Coordination Chemistry and Organometallics
G.A. Razuvaev Institute of Organometallic Chemistry
2015-2025
National Research Nuclear University MEPhI
2015-2020
Russian Academy of Sciences
2014
A series of dimethylindium complexes general formula (R-ONN)InMe2 (R = H (1), Me (2), Cl (3), NO2 (4)) have been synthesized by the reaction Me3In with an appropriate...
The review summarizes and analyzes the currently know data on synthesis, molecular electronic structures magnetic properties of bi-, tri- tetraradical complexes containing a diamagnetic metal ion redox-active ligands in paramagnetic form. bibliography includes 193 references.
Novel O,N-heterocyclic germylenes were examined as catalysts for cyanosilylation and hydroboration of benzaldehyde.
A series of new charge transfer (CT) chromophores "α-diimine-MII-catecholate" type (where M is 3d-row transition metals-Cu, Ni, Co) were derived from 4,4'-di-tert-butyl-2,2'-bipyridyl and 3,6-di-tert-butyl-o-benzoquinone (3,6-DTBQ) in accordance with three modified synthetic approaches, which provide high yields products. square-planar molecular structure inherent for monomeric [CuII(3,6-Cat)(bipytBu)]∙THF (1) NiII(3,6-Cat)(bipytBu) (2) chromophores, while dimeric complex...
Two new heteroleptic cobalt(II) complexes (3,6-Cat)Co(R-DAD) (where (3,6-Cat)2− is a dianion of 3,6-di-tert-butyl-o-benzoquinone, R-DAD diisopropyl-1,4-diaza-1,3-butadiene (R = i-Pr (1)) or dicyclohexyl-1,4-diaza-1,3-butadiene c-Hex (2)) have been synthesized and characterized in detail by IR, UV–Vis–NIR spectroscopy, elemental analysis. The molecular structure 1 was determined X-ray diffraction Magnetic properties 2 were measured both solid state solution. According to the single-crystal...
A number of pentacoordinated gallium complexes iSQ2GaR (1–7) (R = Et (1), Me (2), N3 (3), Cl (4), Br (5), I (6), NCS (7)) where iSQ is a radical anion 4,6-di-tert-butyl-N-(2,6-diisopropylphenyl)-o-iminobenzoquinone were synthesized, and crystalline samples 1–7 characterized using magnetic susceptibility measurements. The character exchange interaction between spins o-iminosemiquinonate radicals was found to be strongly influenced by the nature apical substituent. antiferromagnetic coupling...
The new bis-o-iminobenzosemiquinonate nickel and cobalt complexes (imSQt-Bu)2M (M = Ni (1), Co (2)), where imSQ is a radical anion of 4,6-di-tert-butyl-N-(tert-butyl)-o-iminobenzoquinone, were synthesized characterized in detail. molecular structures 1 2 have been established by single-crystal X-ray analysis. metal atoms distorted tetrahedral environment, the dihedral angles between planes two ligands are approximately 80° both complexes. According to structural spectroscopy data along with...
The reactivity of <italic>o</italic>-amidophenolate indium(<sc>iii</sc>) complexes towards different oxidants was investigated. mono- and biradical <italic>o</italic>-iminobenzosemiquinonato indium(<sc>III</sc>) were synthesized characterized as a result.
The series of pentacoordinated bis‐ o ‐iminobenzosemiquinonato complexes with general formula (imSQ) 2 MR where imSQ – is a radical anion 4,6‐di‐ tert ‐butyl‐ N ‐(2,6‐di‐isopropylphenyl)‐ ‐iminobenzoquinone (M = Al, Ga, In; R Akl, Hal, 3 , NCS) has been expanded through synthesis six new [M In, Me ( 1 ), Br 5 Cl 6 ); M OPh 16 NCO 17 23 )]. In all except for Alk the strong antiferromagnetic exchange coupling between organic radicals, conditioned by presence pathway superexchange, takes place....
Three new 3D metal–organic frameworks of lanthanum based on mixed anionic ligands, [(La2(pQ)2(BDC)4)·4DMF]n, [(La2(pQ)2(DHBDC)4)·4DMF]n, [(La2(CA)2(BDC)4)·4DMF]n (pQ—dianion 2,5-dihydroxy-3,6-di-tert-butyl-para-quinone, CA—dianion chloranilic acid, BDC-1,4-benzenedicarboxylate, DHBDC-2,5-dihydroxy-1,4-benzenedicarboxylate and DMF-N,N′-dimethylformamide), were synthesized using solvothermal methodology. Coordination polymers demonstrate the rare xah or 4,6T187 topology a framework. The...
A series of complexes metal halides with unreduced quinone-type ligands have been synthesized and characterized in detail. The 3,6-di-tert-butyl-o-benzoquinone (1) 4,6-di-tert-butyl-N-aryl-substituted o-iminobenzoquinones (2–5) (aryl is 2,6-dimethylphenyl 2, 2-methyl-6-ethylphenyl 3, 2,6-diethylphenyl 4, 2,6-diisopropylphenyl 5) were used to obtain the molecular 12 group as well indium(III) iodide. structures five complexes, bearing an form redox-active ligand, established by single-crystal...