- Metal complexes synthesis and properties
- X-ray Diffraction in Crystallography
- Crystallization and Solubility Studies
- Magnetism in coordination complexes
- Metal-Catalyzed Oxygenation Mechanisms
- Lanthanide and Transition Metal Complexes
- Free Radicals and Antioxidants
- Organometallic Compounds Synthesis and Characterization
- Metal-Organic Frameworks: Synthesis and Applications
- Crystal structures of chemical compounds
- Synthesis and Characterization of Heterocyclic Compounds
- Inorganic and Organometallic Chemistry
- Electron Spin Resonance Studies
- Vanadium and Halogenation Chemistry
- X-ray Spectroscopy and Fluorescence Analysis
- Electrochemical Analysis and Applications
- Nonlinear Optical Materials Research
- Thermal and Kinetic Analysis
- Synthesis and Reactions of Organic Compounds
- Electron and X-Ray Spectroscopy Techniques
- Crystallography and molecular interactions
- Chemical and Physical Properties in Aqueous Solutions
- Railway Systems and Materials Science
- Oxidative Organic Chemistry Reactions
- Ruminant Nutrition and Digestive Physiology
Awadhesh Pratap Singh University
2013-2022
National Dairy Research Institute
2018
National Institute of Technology Rourkela
1967
Quantum error correction with erasure qubits promises significant advantages over standard due to favorable thresholds for errors. To realize this advantage in practice requires a qubit which nearly all errors are such errors, and the ability check without dephasing qubit. We demonstrate that “dual-rail qubit” consisting of pair resonantly coupled transmons can form highly coherent qubit, where transmon <a:math xmlns:a="http://www.w3.org/1998/Math/MathML"...
Large area reduced graphene oxide (RGO) thin films have been grown using pulsed laser deposition (PLD) technique. A very large carrier mobility of 372 cm2 V-1s-1 has observed in a PLD RGO film with sp2 carbon fraction 87% along narrow Raman 2D peak profile. The and carbon/oxygen ratios are tuned through growth parameters, these estimated from X-ray photoelectron spectroscopy (XPS) data. electrical properties the comprehended by intensity between different optical phonon vibrational modes...
Three new copper(<sc>ii</sc>) complexes, <italic>viz</italic>., [Cu(L)(NO<sub>3</sub>)(H<sub>2</sub>O)]H<sub>2</sub>O <bold>1</bold>, [Cu(L)(H<sub>2</sub>O)<sub>2</sub>]NO<sub>3</sub><bold>2</bold> and [Cu<sub>2</sub>(L)<sub>2</sub>(pyrazine)](ClO<sub>4</sub>)<sub>2</sub>·4H<sub>2</sub>O <bold>3</bold>, were prepared using a biomimetic synthesis strategy [HL = 4-chloro-2-{(<italic>E</italic>)-[2-(pyridin-2-yl)hydrazinylidene]methyl}phenol]. In complex stacking of chelates rings was observed.
The two new nickel(II) complexes, [Ni(HL)(L)](NO3)∙H2O (1) and [Ni(L)2] (2) (where HL/L = N′-[(E)-phenyl(pyridin-2-yl)methylidene]benzohydrazide), have been synthesized characterized by elemental analysis, spectroscopic, magnetic susceptibility, cyclic voltammetric measurements. Single-crystal X-ray analysis of has revealed the presence a distorted octahedral geometry around nickel(II). spectral characterizations confirmed existence keto-enol form ligands in complexes. electronic structures...
A diverse set of new copper(<sc>ii</sc>) complexes synthesized as possible models for antioxidant superoxide dismutase mimics.