A5085004190- Phase Equilibria and Thermodynamics
- Chemical Thermodynamics and Molecular Structure
- Thermodynamic properties of mixtures
- Carbon Dioxide Capture Technologies
- CO2 Sequestration and Geologic Interactions
- Enhanced Oil Recovery Techniques
- Hydrocarbon exploration and reservoir analysis
- Refrigeration and Air Conditioning Technologies
- Scientific Measurement and Uncertainty Evaluation
- Groundwater flow and contamination studies
- Atmospheric and Environmental Gas Dynamics
- Calibration and Measurement Techniques
- Chemical Looping and Thermochemical Processes
- Geophysical and Geoelectrical Methods
- Spacecraft and Cryogenic Technologies
- Calcium Carbonate Crystallization and Inhibition
- Mine drainage and remediation techniques
- Industrial Gas Emission Control
- NMR spectroscopy and applications
- Advanced Thermodynamic Systems and Engines
- Catalytic Processes in Materials Science
- High voltage insulation and dielectric phenomena
- Microbial bioremediation and biosurfactants
- Heat and Mass Transfer in Porous Media
- Molecular Spectroscopy and Structure
Universidad de Valladolid
2008-2024
University of Aberdeen
2013-2024
Imperial College London
2012-2015
Solid metal oxides for carbon capture exhibit reduced adsorption capacity following high-temperature exposure, due to surface area reduction by sintering. Furthermore, only low-coordinate corner/edge sites on the thermodynamically stable (100) facet display favorable binding toward CO2, providing inherently low capacity. The (111) facet, however, exhibits a high concentration of sites. In this work, MgO(111) nanosheets displayed as well ∼65% increase in despite ∼30% sintering (0.77 mmol g–1...
We report the solubility of carbon dioxide in CaCl2(aq) and MgCl2(aq) at molalities (1, 3, 5) mol·kg–1, temperatures (308 to 424) K pressures up 40 MPa. also CO2 a synthetic formation brine containing 0.910 mol·kg–1 NaCl 0.143 KCl over same ranges temperature pressure. The expanded uncertainties 95 % confidence are 0.03 temperature, between (0.08 0.15) MPa bubble pressure 0.00015 mole fraction solution its point. results show strong salting-out effect, whereby declines with increasing...
Many countries have assigned an indispensable role for carbon capture and storage (CCS) in their national climate change mitigation pathways. However, CCS deployment has stalled most with only limited commercial projects realised mainly hydrocarbon-rich enhanced oil recovery. If the Paris Agreement is to be met, then this progress must replicated widely, including hydrocarbon-limited countries. In study, we present a novel source-to-sink assessment methodology based on hubs clusters approach...
A high-pressure flow calorimeter is used to determine isobaric heat capacities for aqueous solutions of some amines such as MEA, DEA TEA, DMAE, MDEA, PZ from T = (293.15 353.15) K and up 25 MPa. The experimental device can measure with an estimated total uncertainty better than 1% a coverage factor k 2. capacity values are analysed in conjunction their temperature pressure dependencies. Furthermore, empirical equations proposed fit functions given conditions, this kind mixtures, obtaining...
This work aims to address the technical concerns related thermodynamic characterization of gas mixtures blended with hydrogen for implementation as a new energy vector. For this purpose, experimental speed sound measurements have been done in gaseous and supercritical phases two binary nitrogen using most accurate technique available, i.e., spherical acoustic resonator, yielding an expanded ($k$ = 2) uncertainty only 220 parts $10^{6}$ (0.022%). The cover pressure range between (0.5 20) MPa,...
This work reports new experimental data on densities and viscosities of (CO2 + n-pentane) n-hexane) mixtures at high pressures temperatures. The were measured by a vibrating-tube densimeter with an expanded uncertainty (k = 2) smaller than 1.8 kg·m−3 six isotherms (from 273.15 K to 373.15 K), twelve starting 5 MPa up 100 MPa, CO2 molar compositions 0 0.6). vibrating-wire viscometer the corresponding relative 0.016 five MPa), two (0.1 0.3). fitted semiempirical Tammann-Tait equation for...
Abstract The zeta potential is a measure of electric at the mineral‐electrolyte interfaces. natural sandstones depends on mineralogy, electrolyte pH, concentration, composition, amount dissolved CO 2 , and temperature. We report for first time measured clayey sandstone comprising quartz, kaolinite, illite, albite microcline saturated with NaCl solutions supercritical conditions. Our results demonstrate that potentials in samples conditions are significantly different from similar...
Vapor–liquid equilibria, data containing ethyl 1,1-dimethylethyl ether (ETBE) as an synthesized from ethanol of biological origin, are presented giving isothermal p−x−y for the ternary system + 1-hexene cyclohexane and two binary systems involved at 313.15 K. A static technique consisting total pressure cell was used measurements. Data reduction by Barker’s method provides correlations GE, using Margules equation Wohl expansion system. Wilson, NRTL, UNIQUAC models have also been applied to...