Santiago D. Barrionuevo

ORCID: 0000-0002-4870-343X
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About
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Research Areas
  • Carbon and Quantum Dots Applications
  • Graphene research and applications
  • Electrochemical sensors and biosensors
  • Advanced biosensing and bioanalysis techniques
  • Nanocluster Synthesis and Applications
  • Quantum Dots Synthesis And Properties
  • Advanced Photocatalysis Techniques
  • Molecular Sensors and Ion Detection
  • Carbon Nanotubes in Composites
  • Solar-Powered Water Purification Methods
  • Graphene and Nanomaterials Applications
  • Analytical chemistry methods development
  • Nanopore and Nanochannel Transport Studies

Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas
2019-2024

Consejo Nacional de Investigaciones Científicas y Técnicas
2019-2024

Universidad Nacional de La Plata
2021-2024

The layer stacking morphology in nanocarbons is paramount for achieving new properties and outperforming applications. Here, we demonstrate that graphene quantum dots (GQDs) retain crystallinity a structure from CVD grown on Ni foam. Our results reveal GQD subdomains comprise few-layer the AB···AB ABC···ABC configuration. HR-TEM images along with multiple-approach characterization (XRD, XPS, UV–vis, AFM, ATR-IR) exhibit ∼3.0 to ∼8.0 nm crystalline GQDs 2–6 layers thick indicating disk-shape...

10.1021/acs.jpcc.3c06871 article EN The Journal of Physical Chemistry C 2024-01-10

Herein, we report the synthesis of graphene quantum dots (GQDs) functionalized with 1,5-diphenylcarbazone for selective quantification Fe in wine, via front-face fluorescence.Crystalline GQDs are obtained a clean and relatively size-controlled based on electrochemical exfoliation from foam.The product was later to solely detect 3+ amongst various other ions present within sample.The detection is quenching fluorescence emission nanomaterial presence analyte, which follows linear relationship...

10.1016/j.talo.2023.100202 article EN cc-by-nc-nd Talanta Open 2023-03-07

A computational laboratory experiment is carried out to investigate the size-, geometry-, and chemistry-dependent properties of small molecules known as polycyclic aromatic hydrocarbons (PAHs) at Facultad de Ingeniería (Universidad Nacional La Plata, UNLP), Buenos Aires, Argentina. This research was adapted for upper-division undergraduate initial graduate education levels. Due adverse circumstances pandemic, students were challenged perform theoretical calculations on a regular computer...

10.1021/acs.jchemed.1c00879 article EN Journal of Chemical Education 2022-01-03

A combination of chemically functionalized-graphene quantum dots with a machine learning algorithm permits selectivity and accurate detection Fe 3+ Hg 2+ ions in real water samples.

10.1039/d3en00702b article EN Environmental Science Nano 2024-01-01

The way graphene (GDs) and carbon dots (CDs) are synthesized combined with TiO2 determine their photoelectrochemical efficiency upon UV visible LED lights. GDs CDs obtained by relatively unexplored top-down methods conventional bottom-up methods, respectively. Top-down consist in the seedless growth of ZnO nanoparticles on surface electrochemical cleavage grown Ni foam. These later different approaches such as solution mixing, adsorption via APTES linkers, drop-casting an already formed...

10.1021/acsanm.1c01295 article EN ACS Applied Nano Materials 2021-07-13

Achieving versatile routes to generate crystalline carbon-based nanostructures has become a fervent pursuit in photocatalysis-related fields. We demonstrate that the direct electrooxidation of ethanol, performed on Ni foam, yields ultra-small and highly graphene-like structures named carbon quantum dots (CQDs). perform simulations various sp2 sp3 domains order understand optical properties CQDs by accounting their contribution as absorbance/luminescent centers overall response. Experiments...

10.1039/d3tc01774e article EN Journal of Materials Chemistry C 2023-01-01

Herein, we report the synthesis of graphene quantum dots (GQDs) functionalized with 1,5-diphenylcarbazone for selective quantification Fe, within wine beverages, via front-face fluorescence. GQDs are obtained a clean and relatively size-controlled based on electrochemical exfoliation from foam. The product was later to solely detect Fe various other ions present sample. detection mechanism relays quenching emission material by Fe3+, which follows Stern-Volmer model, that proposes linear...

10.2139/ssrn.4341052 article EN 2023-01-01
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