A5091746836- Asymmetric Hydrogenation and Catalysis
- Catalysis for Biomass Conversion
- Nanomaterials for catalytic reactions
- Catalysis and Hydrodesulfurization Studies
- Machine Learning in Materials Science
Delft University of Technology
2021
Abstract Any catalyst should be efficient and stable to implemented in practice. This requirement is particularly valid for manganese hydrogenation catalysts. While representing a more sustainable alternative conventional noble metal-based systems, catalysts are prone degrade under catalytic conditions once operation temperatures high. Herein, we report highly Mn(I)-CNP pre-catalyst which gives rise the excellent productivity (TOF° up 41 000 h −1 ) stability (TON 200 000) catalysis. system...
Homogeneous hydrogenation catalysts based on metal complexes provide a diverse and highly tunable tool for the fine chemical industry. To fully unleash their potential, fast effective methods evaluation of catalytic properties are needed. In turn, this requires changes in experimental approaches to test evaluate performance processes. Design experiment combined with statistical analysis can enable time- resource-efficient experimentation. work, we employ set different models obtain detailed...
The foremost requirement for any catalyst to beimplemented in practice is its efficiency and stability. Thisrequirement particularly valid manganese hydrogenation catalysts representing more sustainable alternatives conventional noble metal-based systems. Herein, we report a highly efficient Mn(I)-CNP pre-catalyst featuring phosphine arm hemilability, which gives rise the excellent productivity (TOF° up 41 000 h-1) outstanding stability (TON 200 000) catalysis. This system enables...
<div>The foremost requirement for any catalyst to be</div><div>implemented in practice is its efficiency and stability. This</div><div>requirement particularly valid manganese hydrogenation catalysts representing more sustainable alternatives conventional noble metal-based systems. Herein, we report a highly efficient Mn(I)-CNP pre-catalyst featuring phosphine arm hemilability, which gives rise the excellent productivity (TOF° up 41 000 h-1) outstanding...