A5058870752- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Synthetic Organic Chemistry Methods
- Organometallic Complex Synthesis and Catalysis
- Dendrimers and Hyperbranched Polymers
- Advanced Polymer Synthesis and Characterization
- Crystallography and molecular interactions
- Organoboron and organosilicon chemistry
- Inorganic Chemistry and Materials
- biodegradable polymer synthesis and properties
- Electrochemical sensors and biosensors
- Supramolecular Chemistry and Complexes
- Asymmetric Hydrogenation and Catalysis
- Polymer Surface Interaction Studies
- Conducting polymers and applications
- Advanced Sensor and Energy Harvesting Materials
- Carbon dioxide utilization in catalysis
Chinese Academy of Sciences
2017-2021
State Key Laboratory of Polymer Physics and Chemistry
2017-2021
Changchun Institute of Applied Chemistry
2017-2021
University of Chinese Academy of Sciences
2020-2021
Changchun University of Chinese Medicine
2021
China University of Mining and Technology
2014
Abstract Hydrogenolysis of the scorpionate‐supported barium alkyl complex (Tp Ad,iPr )Ba[CH(SiMe 3 ) 2 ](THF) =hydrotris(3‐adamantyl‐5‐isopropyl‐pyrazolyl)borate) afforded dinuclear hydrido [(Tp )Ba(μ‐H)] ( ), which was characterized by NMR spectroscopy and single‐crystal X‐ray analysis. Exposure with 1 atm CO resulted in a reductive coupling process to form cis‐ethendiolate dianion ). Reaction one equivalent PhC≡C−C≡CPh gave 1,4‐diphenyl‐2‐butyne‐1,4‐diyl {[(Tp )Ba] (PhCH−C≡C−CHPh) 4
Mononuclear calcium unsubstituted alkyl complex [(Tp<sup>Ad,iPr</sup>)Ca{(CH<sub>2</sub>)<sub>4</sub>Ph}(THP)], proposed as the catalytic alkene hydrogenation intermediate, was isolated for first time.
Abstract Hydrogenolysis of the scorpionate‐supported barium alkyl complex (Tp Ad,iPr )Ba[CH(SiMe 3 ) 2 ](THF) =hydrotris(3‐adamantyl‐5‐isopropyl‐pyrazolyl)borate) afforded dinuclear hydrido [(Tp )Ba(μ‐H)] ( ), which was characterized by NMR spectroscopy and single‐crystal X‐ray analysis. Exposure with 1 atm CO resulted in a reductive coupling process to form cis‐ethendiolate dianion ). Reaction one equivalent PhC≡C−C≡CPh gave 1,4‐diphenyl‐2‐butyne‐1,4‐diyl {[(Tp )Ba] (PhCH−C≡C−CHPh) 4
Water-soluble electrically conductive polymer poly(3,4-ethylenedioxythiophene) (PEDOT) was synthesized by the enzymatic-catalyzed method using 3,4-ethylenedioxythiophene (EDOT) as monomer, poly(styrenesulfonate) (PSS) water-soluble polyelectrolyte, horseradish peroxidase enzyme catalyst, and hydrogen peroxide (H2O2) oxidant. Fourier transform infrared spectra UV–vis absorption confirm successful polymerization of PEDOT. Dynamic light scattering data formation a stable PEDOT:PSS aqueous...
A tri-functionalized initiator (IV) based on Blechert's catalyst as a highly efficient ROMP for the living polymerization of norbornene derivatives.
One-shot synthesis of star gradient copolymers with controllable graft density <italic>via</italic> ring-opening metathesis polymerization.