A5021653047- Surface Chemistry and Catalysis
- Block Copolymer Self-Assembly
- Covalent Organic Framework Applications
- Machine Learning in Materials Science
- Theoretical and Computational Physics
- Photonic Crystals and Applications
- Nutrition and Health Studies
- Physical Education and Training Studies
- Surface and Thin Film Phenomena
- Ionic liquids properties and applications
- Children's Physical and Motor Development
- Sports Science and Education
- Mesoporous Materials and Catalysis
- Luminescence and Fluorescent Materials
Maria Curie-Skłodowska University
2019-2024
Faculty (United Kingdom)
2021
Nicolaus Copernicus University
2017
Collegium Medicum in Bydgoszcz
2017
The on-surface synthesis of organic polymers has been recently recognized as a useful method to create low-dimensional covalently bonded structures with tailorable topology and functions. In this work, the Monte Carlo simulation was used study metal–organic precursors covalent formed in Ullmann-type coupling reaction halogenated naphthalene derivatives. To purpose, coarse-grained model proposed which monomers, represented by pair interconnected segments, two-coordinate metal atoms (one...
Functionalized polycyclic aromatic hydrocarbons (PAHs) have been recently recognized as promising building blocks for surface-assisted polymerization reactions producing low-dimensional covalent structures with tailorable properties. In this work, we used the lattice Monte Carlo (MC) simulation method to predict structure of labile metal–(halogenated)anthracene connections preceding formation polymers in Ullmann-type coupling reaction occurring on catalytically active metallic surfaces. To...
Surface-assisted fabrication of molecular network architectures has been a promising route to low-dimensional materials with unique physicochemical properties and functionalities. One versatile way in this field is the Ullmann coupling reaction halogenated organic monomers on catalytically active metallic surfaces. In work, using coarse-grained Monte Carlo simulations, we studied on-surface self-assembly metal-organic precursors preceding covalent Ullman-type linkage tetrahalogenated...
Materials with disordered structures may exhibit interesting properties. Metal–organic frameworks (MOFs) are a class of hybrid materials composed metal nodes and coordinating organic linkers. Recently, there has been growing interest in MOFs structural disorder the investigations amorphous on surfaces. Herein, we demonstrate bottom-up method to construct molecular networks surfaces by selecting two molecule linkers same symmetry but different sizes for preparing two-component samples...
Theoretical calculations predicted multiple outputs of the surface-confined self-assembly metal–organic precursors comprising naphthalene monomeric units with differently distributed halogen atoms.
On-surface polymerization of functional organic molecules has been recently recognized as a promising route to persistent low-dimensional structures with tailorable properties. In this contribution, using the coarse-grained Monte Carlo simulation method, we study initial stage Ullmann coupling doubly halogenated chrysene isomers adsorbed on catalytically active (111) crystalline surface. To that end, focus formation labile metal-organic precursor preceding covalent bonding monomers. Four...
Surface-assisted fabrication of carbon-based covalent architectures has been a promising pathway to low-dimensional materials with special physicochemical properties and functions. In this contribution, the Monte Carlo simulation method was used predict formation metal-organic precursors preceding Ullmann coupling halogenated phenanthrene monomers. To that end, coarse-grained model adsorbing (111) surface, molecules linking adatoms proposed, in which monomers were equipped active centers...
Deterministic fractals have long been considered abstract objects with unique structural properties, and their experimental realization by systematic molecular design has achieved only recently. In this contribution, we demonstrate how the coarse-grained Monte Carlo modeling can be used to predict optimize formation of fractal Sierpiński-type triangular metal–organic precursors on solid substrates. To that end, a mixture suitably functionalized polyaromatics differing in size/shape bivalent...
The diversity of surface-confined metal-organic precursor structures, which recently have been observed experimentally, poses a question how the individual properties molecular building block determine those resulting superstructure. To answer this question, we use Monte Carlo simulation technique to model self-assembly precursors that precede covalent polymerization halogenated PAH isomers. For purpose, few representative examples low-dimensional constructs were studied, and their basic...
Two-dimensional network structures comprising functional organic building blocks have been recently recognized as promising platforms for various physio-chemical processes running in confined spaces. In this study, we present theoretical results of the self-assembly metal-organic precursor networks on a crystalline surface and provide quantitative characteristics these planar architectures. To that end, coarse-grained model adsorbed overlayer halogenated polyaromatic aromatic hydrocarbon...
Abstract On-surface synthesis of C–C covalent low-dimensional nanomaterials is a promising method obtaining structures with tailored and novel physicochemical electric properties. In this contribution, the Monte Carlo simulation approach was proposed to predict topology metal–organic (MO) intermediates formed in Ullmann homocoupling halogenated isomers tetracene. The coarse-grained model polyaromatic hydrocarbons (PAH) haloderivatives divalent copper adatoms on metallic crystal surface (111)...
Sensory Integration (SI) is one of the therapeutic methods created and described by J. Ayres in 1972. In Poland, for a few years, more specialists, also rehabilitators, have followed this concept their work. SI subconscious process, whereby ordering assignment meaning to information acquired senses takes place. The three principal senses, which are: sense touch, proprioception, vestibular system.
Abstract On-surface synthesis of C-C covalent low-dimensional nanomaterials is a promising method obtaining structures with tailored and novel physicochemical electric properties. In this contribution, the Monte Carlo simulation approach was proposed to predict topology metal-organic (MO) intermediates formed in Ullmann homocoupling halogenated isomers tetracene. The coarse-grained model polyaromatic hydrocarbons (PAH) haloderivatives divalent copper adatoms on metallic crystal surface (111)...