A5035594145- Organoselenium and organotellurium chemistry
- Sulfur-Based Synthesis Techniques
- Vanadium and Halogenation Chemistry
- Synthesis and Reactivity of Sulfur-Containing Compounds
- Structural and Chemical Analysis of Organic and Inorganic Compounds
- Organophosphorus compounds synthesis
- X-ray Diffraction in Crystallography
- Organic Chemistry Cycloaddition Reactions
- Crystallization and Solubility Studies
- Molecular Spectroscopy and Structure
- Chemical Synthesis and Reactions
- Selenium in Biological Systems
- Porphyrin and Phthalocyanine Chemistry
- Advanced Chemical Physics Studies
- Chemical Thermodynamics and Molecular Structure
- Chemical Reaction Mechanisms
- Synthesis and biological activity
- Synthesis of heterocyclic compounds
- Chemical Synthesis and Analysis
- Asymmetric Synthesis and Catalysis
- Organic and Molecular Conductors Research
- Organometallic Compounds Synthesis and Characterization
- Advanced NMR Techniques and Applications
- Synthesis and Characterization of Pyrroles
- Medicinal plant effects and applications
A.E. Favorsky Irkutsk Institute of Chemistry
2015-2024
Russian Academy of Sciences
2008-2013
The original goal of this research was to study stereochemistry selenium dihalides addition cycloalkenes and properties obtained products. Remarkable alkene-to-alkene alkene-to-alkyne transfer reactions dibromide PhSeBr were discovered during research. adducts with alkenes or easily exchange SeBr2 other unsaturated compounds, including acetylenes, at room temperature, in acetonitrile. Similar the take place. supposed reaction pathway includes group from seleniranium species alkynes. It found...
Regioselective syntheses of bis-(2-haloalkyl) selenides in excellent yields were developed based on selenium dihalides and terminal alkenes (1-hexene, 1-heptene 1-octene).The addition dichloride dibromide to the occurred via intermediate formation kinetic products, anti-Markovnikov bis-(1haloalk-2-yl) selenides, which further transformed into thermodynamically stable Markovnikov products NaHCO 3 MeOH/CH 2 Cl