A5052421234- Metal-Organic Frameworks: Synthesis and Applications
- Covalent Organic Framework Applications
- Nanomaterials for catalytic reactions
- Polyoxometalates: Synthesis and Applications
- Supramolecular Chemistry and Complexes
- Catalytic Processes in Materials Science
- Supramolecular Self-Assembly in Materials
- Carbon dioxide utilization in catalysis
- Catalysis for Biomass Conversion
- X-ray Diffraction in Crystallography
- Chemical Synthesis and Reactions
- MXene and MAX Phase Materials
- CO2 Reduction Techniques and Catalysts
- Crystallization and Solubility Studies
National Center for Nanoscience and Technology
2021-2023
University of Chinese Academy of Sciences
2021-2023
Beihang University
2021-2022
Chinese Academy of Sciences
2022
Selective aerobic epoxidation of alkenes without any additives is great industrial importance but still challenging because the competitive side reactions including C═C bond cleavage and isomerization are difficult to avoid. Here, we show fabricating Cu(I) single sites in pristine multivariate metal-organic frameworks (known as CuCo-MOF-74) via partial reduction Cu(II) ions during solvothermal reaction. Impressively, CuCo-MOF-74 characteristic with Cu(I), Cu(II), Co(II) sites, they exhibit...
Numerous efforts are being made toward constructing artificial nanopockets inside heterogeneous catalysts to implement challenging reactions that difficult occur on traditional catalysts. Here, the enzyme-mimetic fabricated typical UiO-66 by coordinating zirconium nodes with terephthalate (BDC) ligands and monocarboxylate modulators including formic acid (FC), acetic (AC), or trifluoroacetic (TFA). When used in transfer hydrogenation of alkyl levulinates isopropanol γ-valerolactone (GVL),...
Abstract Natural enzymes exhibit unparalleled selectivity due to the microenvironment around active sites, but how design artificial catalysts achieve similar performance is a formidable challenge for catalysis community. Herein, we report that less selective platinum catalyst becomes highly and industrially relevant hydrosilylation of broad range substrates when porous cage ligand used confinement catalytic site. The more than ten times Karstedt’s while being recyclable. Properties such as...
Selective hydrogenation of quinoline toward 1,2,3,4-tetrahydroquinoline shows great application potential in the production medicine, pesticides and fine chemicals.However, is usually carried out under harsh reaction conditions such as high temperature pressure, thus, it a challenge to achieve selective mild conditions.In this work, we construct platinum nanoparticles (Pt NPs) sandwiched an inner core outer shell composed metal-organic framework synthesized by zirconium chloride...