A5053614169- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Metal-Organic Frameworks: Synthesis and Applications
- Polyoxometalates: Synthesis and Applications
- Catalytic Cross-Coupling Reactions
- Advanced Nanomaterials in Catalysis
- Catalytic C–H Functionalization Methods
- Advanced Sensor and Energy Harvesting Materials
- Hydrogels: synthesis, properties, applications
- Covalent Organic Framework Applications
- Magnetism in coordination complexes
- Chemical Synthesis and Characterization
- Asymmetric Hydrogenation and Catalysis
- Catalytic Alkyne Reactions
- Nanocluster Synthesis and Applications
- TiO2 Photocatalysis and Solar Cells
- Microbial bioremediation and biosurfactants
- Advanced Materials and Mechanics
- Flame retardant materials and properties
- Porphyrin and Phthalocyanine Chemistry
- Organoboron and organosilicon chemistry
- Supramolecular Self-Assembly in Materials
- Cyclopropane Reaction Mechanisms
- Electrospun Nanofibers in Biomedical Applications
- Thermal properties of materials
Changchun University of Technology
2013-2024
Xiamen University of Technology
2007-2023
Northeast Normal University
2008-2020
Guizhou Normal University
2019
Advanced Institute of Materials Science
2019
Lawrence Berkeley National Laboratory
2019
Hainan Normal University
2013-2019
North China University of Science and Technology
2016
South Central Minzu University
2015
Heilongjiang University
2013-2014
Pretty porous POMs: Ionothermal synthesis was applied to prepare POM-based open frameworks. The structural integrity remains unchanged until 300 °C; most importantly, the bulky tetrabutylammonium cations within their nanosized channels can be replaced by transition-metal ions through a cation-exchange process, and subsequent gas adsorption measurements confirm permanent porosity. Detailed facts of importance specialist readers are published as "Supporting Information". Such documents...
Ligand-free Pd(OAc)(2) was found to catalyze very efficiently the direct arylation of imidazo[1,2-a]pyridines at C3 under low catalyst concentration. The reaction can be performed employing as little 0.1-0.01 mol % with electron-deficient and some electron-excessive aryl bromides.
One new polyoxometalate compound H3(Tea)(Bmim)3[P2W18O62]·3H2O (Tea = triethylamine, Bmim 1-methyl-3-ethylimidazole) (1) and three polyoxometalate-based metal−organic frameworks (PMOFs) CuII(Bbi)1.5(H2Bbi)2[P2W18O62] (Bbi 1,1-(1,4-butanediyl)-bis(imidazole)) (2), CuII2.5(Mimin)(HMimin)(Bbi)3[P2W18O62]·3H2O (Mimin methylimidazol) (3), CuII(Bbtz)(H2Bbi)(H2Btp)[P2W18O62] (Bbtz 1,4-bis(triazol-1-ylmethyl)benzene, Btp 1,3-Bis(1,2,4-triazol-1-yl)propane) (4) have been synthesized under ionothermal...
Eight polyoxometalate (POM)-based frameworks were synthesized under hydrothermal conditions, using different octamolybdate isomers (Mo8) and copper-organic fragments or organic units in the presence of bases. These compounds are named as [CuI(bix)][(CuIbix)(δ-Mo8O26)0.5] (1), H(CuIbix)[(CuIbix)2(β-Mo8O26)]·2H2O (2), H3[CuI(bix)2(β-Mo8O26)0.5](β-Mo8O26)0.5·2H2O (3), (H2bix)2(β-Mo8O26)0.5(β-Mo8O26)0.5·H2O (4), (H2bix)[(Hbix)2(γ-Mo8O26)]·2H2O (5), H2bix(γ-Mo8O26)0.5·H2O (6),...
By adjusting the molar ratio of reactants H3PO4 and Na2MoO4, four new metal–organic frameworks, namely, CoH(bix)4[PMoVI8VV4O40(VIVO)2] (1), (H2bix)2(NaHP2Mo5O23)·2H2O (2), H2(bix)4[Cd(H2O)4][Cd(HPO4)4(H2PO4)4(MoO2)12 (OH)6]·10H2O (3) (H2en)3(Co3P4Mo4O28) (4) (bix = 1,4-bis(imidazol-1-ylmethyl)benzene, en 1,2-ethylenediamine), have been hydrothermally prepared characterized by elemental analyses, IR spectroscopy, TG single-crystal X-ray diffraction. Compound 1 consists straight chains based...
Five unique Keggin-type polyoxometalate (POM)-based metal–organic frameworks (POMFs), namely [CH2L1]2[(CuL12)(PMoVI9MoV3O40)] (1), [Zn0.5(H2O)(L1)][Zn(L1)1.5Cl][H2L1]0.5[PMo12O40]·1.25H2O (2), (TBA)[Cu(H2O)2L12][PMo12O40] (3), [Cu2(H2O)2(L1)3][PMVI11MoVO40] (4), (H2L2)0.5[(CuIL2)2(PMo12O40)]·H2O (5), L1 = 4,4′-bis((1H-1,2,4-triazol-1-yl)methyl)-biphenyl, L2 1,4-bis((1H-1,2,4-triazol-1-yl)methyl)-benzene, have been synthesized under ionothermal conditions. According to single-crystal data, 1...
Abstract The palladium‐catalyzed direct arylation of furans or thiophenes that contained secondary carboxamides at the C2 position proceeded regioselectively either C3 C5 positions, depending on reaction conditions. nature base was crucial for controlling regioselectivity reaction. We had previously observed that, in presence potassium acetate, favored. Herein, we report use cesium carbonate as and xylene solvent selectively afforded C3‐arylated thiophenes. reactivity furan‐2‐carboxamides...
Three hybrid networks based on octamolybdate building units, Cu(I)(8)BBTZ(6)[(α-Mo(8)O(26))(β-Mo(8)O(26))] (1), (Cu(I)BBTZ)(4)[Mo(7)Cu(II)O(24)(H(2)O)(2)]·6H(2)O (2), and Cu(II)Cu(I)(2)BBTZ(5)[β-Mo(8)O(26)] (3) (BBTZ = 1,4-bis(1,2,4-triazol-1-ylmethyl)benzene), have been synthesized under ionothermal conditions structurally characterized by single-crystal X-ray diffraction. 1 exhibits a rare 3D three-fold self-penetration network (SPN) structure, in which the interpenetrating polymer (IPN)...
Abstract The palladium‐catalysed direct arylation of methyl 2‐furoate with aryl bromides was studied. use KOAc as the base, dimethylacetamide (DMAc) solvent and Pd(OAc) 2 catalyst found to give 5‐arylfurans regioselectively without decarboxylation. These 5‐aryl‐2‐furoates gave 2,5‐diarylfurans by decarboxylative coupling using catalyst. Methyl thus represents a convenient alternative substrate furan for synthesis mono‐ or poly‐arylated furans.
Two novel metal–organic frameworks (MOFs) based on different tetradentate in situ ligands, CuI3(L1)2(L2)[PMoVI8VV4O40(VIVO)2]·2H2O (1) and [CuI2Cl2(L3)] (2) (L1 = 1,4-bis(imidazol-1-ylmethyl)benzene, L2 1,2,4,5-tetra(4-pyridyl)-benzene L3 a-1-hydroxy-e,e,e,e-1,2,4,5-tetra(4-pyridyl)cyclohexane) have been rationally hydrothermally synthesized characterized by elemental analyses, IR spectroscopy, TG single-crystal X-ray diffraction, respectively. Here, compound 1 represents the first example...
With the use of a flexible N-donor ligand 1,3-bis(4-pyridyl)propane (bpp), new porous framework with Wells-Dawson clusters as nodes and Ni2+ ions linkers, [Ni(bpp)(H2O)2]3[P2W18O62]·∼24H2O (1), has been successfully obtained. Topological analysis indicates that 1 possesses perovskite structure. As framework, displays adsorption behavior toward H2O CH3OH.
POMs sorgen für Poren: Eine Ionothermalsynthese führte zu porösen offenen Gerüsten auf Polyoxometallat(POM)-Basis, deren Strukturen beim Erwärmen bis 300 °C unverändert bleiben. Die sperrigen Tetrabutylammonium-Kationen in den Nanokanälen können außerdem gegen Übergangsmetallionen ausgetauscht werden. Gasadsorptionsmessungen bestätigen die permanente Porosität.
Background: Protein phosphorylation is one of the most important Post-translational Modifications (PTMs) occurring at amino acid residues serine (S), threonine (T), and tyrosine (Y). It plays critical roles in protein structure function predicting. With development novel high-throughput sequencing technologies, there are a huge amount sequences being generated stored databases. Objective: great importance both basic research drug to quickly accurately predict which S, T, or Y can be...
High strength hydrogels with programmable shape-memory and notch insensitive abilities.
A 12-connected metal-organic framework based on an unprecedented cyclic Cu(12) cluster with a large internal cavity has been prepared, and its cation exchange property was determined.