A5024898562- X-ray Diffraction in Crystallography
- Crystallization and Solubility Studies
- Electrochemical Analysis and Applications
- Organometallic Complex Synthesis and Catalysis
- Ionic liquids properties and applications
- Crystallography and molecular interactions
- Inorganic Fluorides and Related Compounds
- Chemical and Physical Properties in Aqueous Solutions
- Gas Sensing Nanomaterials and Sensors
- Inorganic and Organometallic Chemistry
- Fluorine in Organic Chemistry
- Electrochemical sensors and biosensors
- Advanced biosensing and bioanalysis techniques
- Magnetism in coordination complexes
- Advanced Chemical Physics Studies
- Synthesis and characterization of novel inorganic/organometallic compounds
- Conducting polymers and applications
- Thermodynamic properties of mixtures
- Luminescence and Fluorescent Materials
- Free Radicals and Antioxidants
- Metal-Catalyzed Oxygenation Mechanisms
- Atmospheric chemistry and aerosols
- Molecular Spectroscopy and Structure
- N-Heterocyclic Carbenes in Organic and Inorganic Chemistry
- Metal-Organic Frameworks: Synthesis and Applications
Qingdao University
2015-2023
North University of China
2019-2022
Qingdao Center of Resource Chemistry and New Materials
2020-2021
South China Normal University
2012-2019
Beijing Institute of Technology
2015
MXene-derived nanostructures provide the possibility of meeting requirements strong absorption, thin thickness and flexible layer for electromagnetic (EM) wave absorption. However, exploration pure well-intercalated MXene nanosheets efficient EM absorption is still in nascent stages. Herein, Ti3C2Tx with solvent-manipulated properties were achieved via ultrasonication-solvothermal treatment bulk different solvents including dimethylformamide (DMF), ethanol, dimethyl sulfoxide (DMSO),...
A novel class of inorganic salts wherein the superalkali occupies anionic site, termed superalkalides, M<sup>+</sup>(en)<sub>3</sub>M<sub>3</sub>′O<sup>−</sup> (M, M′ = Li, Na, and K) have been designed predicted to be candidates for NLO materials.
Mustard gas poses a substantial concern for homeland security, and the development of sensors facile, rapid, highly sensitive, selective detection mustard simulant is much desirable. Herein, new benzimidazole-containing covalent organic framework (COF), termed BABE-TFPy COF, was synthesized by Schiff base condensation 1-(4,7-bis(4-aminophenyl)-1H-benzoimidazole-2-yl)ethan-1-ol (BABE) with 1,3,6,8-tetrakis(4-formylphenyl)pyrene (TFPy). By virtue its crystallinity, high porosity, excellent...
Ether-functionalized ionic liquids (ILs) have successfully been employed in diverse applications, but their interactions with other solvents are not understood well. In this work, mixtures of 1-methoxyethyl-3-methylimidazolium bis(fluorosulfonyl)imide (EOMIMFSI) and dimethylsulfoxide (DMSO) studied terms solution structure hydrogen bonding interactions. The corresponding alkyl-substituted IL 1-ethyl-3-methylimidazolium (EMIMFSI) is analyzed for comparison. A combination FTIR spectroscopy,...
EMIMTFSI/BpyTFSI and benzene rings formed C–H⋯π bonds, which played a crucial role in capturing aromatic compounds.
A nickel-nickel-bonded complex, [{Ni(μ-L(.-))}2] (1; L=[(2,6-iPr2C6H3)NC(Me)]2), was synthesized from reduction of the LNiBr2 precursor by sodium metal. Further controllable 1 with 1.0, 2.0 and 3.0 equiv Na, respectively, afforded singly, doubly, triply reduced compounds [Na(DME)3]·[{Ni(μ-L(.-))}2] (2; DME=1,2-dimethoxyethane), [Na(Et2O)]Na[(L(.-))Ni-NiL(2-)] (3), [Na(Et2O)]2Na[L(2-)Ni-NiL(2-)] (4). Here L represents neutral ligand, L(.-) denotes its radical monoanion, L(2-) is dianion. All...
The α-diimine nickel dibromo complex LNiBr2 (L = [(2,6-iPr2C6H3)NC(Me)]2) reacts with various amounts of potassium metal and phenazine (Phz) to afford the complexes [LNi(η4-C4-Phz)] (1) [K(DME)]2[(LNi)2(μ-η1:η1-N,N-Phz)] (2), in which Phz molecule adopts significantly different coordination modes oxidation states Phz, Ni, L.
Three sizes of atomically precise tiara-like structural Nin(SR)2n (n = 4, 5 and 6) are co-synthesized by a one-pot method isolated using thin layer chromatography. The molecular formulas Ni5(SR)10 Ni6(SR)12 determined matrix-assisted laser desorption ionization mass spectrometry, the structures Ni4(SR)8 proved single-crystal X-ray crystallography. Nuclear magnetic resonance shows that has similar structure too. electrochemical gap enlarges with increase cluster size, which agrees calculated...
Reactions of the dimeric cobalt complex [(L(-) Co)2 ] (1, L=[(2,6-iPr2 C6 H3 )NC(Me)]2 ) with polyarenes afforded a series mononuclear and dinuclear complexes: [LCo(η(4) -anthracene)] (2), [LCo(μ-η(4) :η(4) -naphthalene)CoL] (3), -phenanthrene)CoL] (4). The pyrene complexes [{Na2 (Et2 O)2 }{LCo(μ-η(3) :η(3) -pyrene)CoL}] (5) O)3 }{LCo(η(3) -pyrene)}] (6) were obtained by treating precursor 1 followed reduction Na metal. These contain three potential redox active centers: metal both α-diimine...
A series of nickel mono(alkene) complexes, [LNi(alkene)], which consist nickel(0) and neutral α-diimine ligand L (L = [(2,6-iPr2C6H3)NC(Me)]2), have been synthesized. The bonding structures the complexes were studied by X-ray diffraction, spectroscopic methods, DFT computations.
The mechanism and dynamics for the bimolecular reaction of (CH3)2NH with CH3 have been investigated based on G3//MP2/6-311G(d,p) level theory. Our calculations show that when two reactants approach each other, three prereaction complexes, RC1, RC2, RC3, can be formed through van der Waals force or hydrogen bonding. From six routes established. Among routes, (R1 R2) from complex RC1 are main title reaction. R1 R2 abstractions associated HN HCα atoms in DMA, respectively. calculated energy...
A hybrid anode integrating enzymatic hydrolysis of starch by glucoamylase and non-enzymatic oxidation glucose gold nanoparticles is presented to achieve an efficient cascade energy conversion from starch.