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Contact & Profiles
A5060636763
Research Areas
- Marine Sponges and Natural Products
- Synthetic Organic Chemistry Methods
- Organometallic Complex Synthesis and Catalysis
Korea Advanced Institute of Science and Technology
2019
Abstract Development of versatile ruthenium olefin-metathesis catalysts with high activity, stability, and selectivity is a continuous challenge. Here we report highly controllable using readily accessible N -vinylsulfonamides as carbene precursors. Catalyst initiation rates were controlled in straightforward manner, from latent to fast initiating, through the facile modulation -vinylsulfonamide ligands. Trifluoromethanesulfonamide-based initiated ultrarapidly even at temperatures low −60 °C...
10.1038/s41467-019-11806-5
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Nature Communications
2019-08-27
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