A5033923077- Asymmetric Hydrogenation and Catalysis
- Chemical Synthesis and Analysis
- Catalysis for Biomass Conversion
- Chemical Synthesis and Reactions
- Synthesis and Catalytic Reactions
- Nanomaterials for catalytic reactions
- Government, Law, and Information Management
- Crystallization and Solubility Studies
- Metal-Organic Frameworks: Synthesis and Applications
- Molecular Sensors and Ion Detection
- Sulfur-Based Synthesis Techniques
- X-ray Diffraction in Crystallography
- Catalytic C–H Functionalization Methods
- Catalytic Cross-Coupling Reactions
- Computational Drug Discovery Methods
- Pharmacogenetics and Drug Metabolism
- Financial Reporting and XBRL
- Microbial Metabolic Engineering and Bioproduction
- Synthesis and Properties of Aromatic Compounds
- Taxation and Legal Issues
- Analytical Chemistry and Chromatography
- Enzyme Catalysis and Immobilization
- Supramolecular Chemistry and Complexes
KU Leuven
2018-2024
National Archives
2001
Abstract Cyclohexylamines are important intermediates in chemical industry, which currently produced from petrochemical sources. Phenols, however, an attractive sustainable feedstock. We here demonstrate the transformation of phenols with ammonia to primary cyclohexylamines. In contrast previously reported chemistry used palladium catalysts, we show that rhodium is excellent catalyst for formation Different parameters were studied and it was shown reaction applicable a scope phenolic...
Only few dynamic kinetic resolution (DKR) systems are known for chiral aliphatic amines due to the difficult racemization of these amines.
In recent decades, considerable research attention has been devoted to new synthetic procedures for thiacyclophanes. Thiacyclophanes are widely used as host molecules the molecular recognition of organic compounds well metals. Herein, we report selective and high-yielding synthesis novel alternate-linked-meta-para-thiacyclophanes. These thiacyclophanes selectively synthesized in procedures. Furthermore, post-functionalization phenolic moieties was successfully performed. The 3D structure...
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The chemoenzymatic dynamic kinetic resolution of β-amino esters is established after detailed evaluation metal-based heterogeneous catalysts for racemization and enzyme resolution.