- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Catalytic Cross-Coupling Reactions
- Catalytic C–H Functionalization Methods
- Organometallic Complex Synthesis and Catalysis
- Lanthanide and Transition Metal Complexes
- Crystallography and molecular interactions
- Immune Response and Inflammation
- Monoclonal and Polyclonal Antibodies Research
- Asymmetric Hydrogenation and Catalysis
- Synthetic Organic Chemistry Methods
- Metal complexes synthesis and properties
- Bacterial Infections and Vaccines
- biodegradable polymer synthesis and properties
- Chemical synthesis and alkaloids
Toscana Life Sciences
2025
The University of Tokyo
2020
Cardiff University
2019
University of Bristol
2018-2019
ConspectusPolyolefins are produced in vast amounts and found so many consumer products that the two most commonly forms, polyethylene (PE) polypropylene (PP), fall into rather sparse category of molecules likely to be known by people worldwide, regardless their occupation. Although widespread, further upgrading properties (mechanical, physical, aesthetic, etc.) through formation composites with other materials, such as polar polymers, fibers, or talc, is huge interest manufacturers. To...
Objective: This manuscript describes an innovative, non-destructive, high-throughput method for the quantification of aluminum hydroxide in aluminum-adjuvanted vaccines, eliminating need reagents and providing real-time results. The is based on a spectrophotometric principle, several model proteins were studied tested with aim to simulate behavior antigens. Methods: As proof concept, MenB vaccine was used, titration (AH) ethylenediaminetetraacetic acid (EDTA) used as orthogonal reference, it...
Intrigued by recent reports on the surprisingly excellent activity of a range cobalt-, iron-, copper-, and nickel-based catalysts in Suzuki biaryl cross-coupling simple aryl boronic acids with halides, we undertook reexamination syntheses representative examples reported precatalysts their application to catalytic reaction. A PNP−Fe pincer complex proved be mixture starting materials; mono-Schiff base cobalt fact bis-ligated adduct monomeric copper(II) PNP–pincer di- or oligomeric copper(I)...
UV-induced photochemical transformations of the paramagnetic [Cr(CO)4(Ph2PCH2CH2CH2PPh2)]+ complex (abbreviated [Cr(CO)4(dppp)]+) in dichloromethane was investigated by CW EPR spectroscopy. Room-temperature UV irradiation results rapid transformation [Cr(CO)4(dppp)]+ into trans-[Cr(CO)2(dppp)2]+. However, low-temperature (77–120 K) reveals presence an intermediate mer-[Cr(CO)3(κ1-dppp)(κ2-dppp)]+ which photochemically transforms The derived spin Hamiltonian parameters for these complexes...