A5061640206- X-ray Diffraction in Crystallography
- Crystallization and Solubility Studies
- Magnetism in coordination complexes
- Lanthanide and Transition Metal Complexes
- Organic and Molecular Conductors Research
- Electron Spin Resonance Studies
- Metal complexes synthesis and properties
- Metal-Catalyzed Oxygenation Mechanisms
- Semiconductor materials and devices
- Metal-Organic Frameworks: Synthesis and Applications
- 3D IC and TSV technologies
- Advanced Photocatalysis Techniques
- Electronic Packaging and Soldering Technologies
- Integrated Circuits and Semiconductor Failure Analysis
- Synthesis and properties of polymers
- Mechanical Behavior of Composites
- Copper-based nanomaterials and applications
- Silicon and Solar Cell Technologies
- Crystallography and molecular interactions
- Inorganic Chemistry and Materials
- Advanced NMR Techniques and Applications
- Epoxy Resin Curing Processes
- Advancements in Photolithography Techniques
- Quantum Dots Synthesis And Properties
- Polymer crystallization and properties
Guizhou University
2015-2024
Hainan Agricultural School
2023
Hainan Normal University
2023
Guizhou Institute of Plant Protection
2021-2023
Wuhan University
2022-2023
State Key Laboratory of Information Engineering in Surveying Mapping and Remote Sensing
2022-2023
IE University
2016-2020
Axcelis Technologies (United States)
2008-2009
Micron (United States)
2003-2005
Georgia Institute of Technology
2000-2002
Employing two benzoate derivatives with different numbers of non-coordinated fluoro-substituents, 2-fluorobenzoic acid (2-Hfba) and 2,6-difluorobenzoic (2,6-Hdfba), new azido-copper coordination polymers, [Cu(2-fba)(N3)(CH3OH)]n (1) [Cu(2,6-dfba)(N3)(CH3OH)]n (2), have been successfully isolated, then structurally magnetically investigated. Single crystal structure analysis demonstrates that the metal cations in resulting compounds are connected by alternating triple-bridge μ-1,1-azido,...
The alteration of the axial N-donor ligands leads to two octahedral Co(<sc>ii</sc>) SIMs with varying easy-plane magnetic anisotropies and dynamic behaviors.
This paper systematically discusses the influence of temperature and humidity on adhesion performance underfill material (epoxy cured with acid anhydride), which was evaluated by die shear test after exposure to various conditions. The inherent strength between passivation is not affected significantly thermal cycling -55/spl deg/C 125/spl for 1000 cycles. decreases increase in investigated range, due decrease modulus temperature. A sharp occurs as increases toward glass transition material....
By elaborately employing a rigid tetrazo macrocyclic ligand, both the designed Co(II) complexes [Co(12-TMC)Py](BF4)2 (1) and [Co(12-TMC)DMF](BF4)Cl (2) (12-TMC = 1,4,7,10-tetramethyl-1,4,7,10-tetraazacyclododecane; Py pyridine; DMF N,N-dimethylformamide) adopt distorted square pyramidal geometry with identical equatorial site but flexible axial ligand environment. Such molecular design enables realization of field-induced single-ion magnets. Importantly, single-molecule magnets display...
Conductive polymer composites showing large positive temperature coefficient (PTC) are made of semi-crystalline as an insulator and a conducting filler, whose concentration is close to the critical volume fraction. In this study, resistivity PTC behavior high density polyethylene (HDPE) filled with different carbon blacks were studied. Among those composites, N660 black PE showed greatest behavior. Carbon particle size, small surface area amount aggregated structure leads amplitude...
Two novel hexanuclear lanthanide clusters (<bold>1</bold> and <bold>2</bold>) were successfully prepared. Magnetic investigations reveal that <bold>1</bold> exhibits remarkable magnetocaloric effect <bold>2</bold> displays interesting slow magnetic relaxation behaviors.
In situ microcalorimetry monitored assembly and coligand induced switching of the magnetic anisotropy sign have been observed in a β-diketonate-Co( ii ) system.
Two isomeric Co(II) complexes with the same general molecular formula of [Co(napy)2(NO3)2] (napy = 1,8-naphthyridine) have been synthesized. X-ray single crystal structural determination demonstrates that two compounds exhibit highly irregular six- (1) and seven-coordinate (2) geometries, respectively. The magnetic measurements, X-band EPR data theoretical calculations were thoroughly investigated. Both show field-induced slow relaxation, which relaxation in 2 is attributed to an easy-plane...
Lane detection is an important and fundamental task in autonomous driving. Modern convolutional neural network (CNN) methods have achieved high performance lane detection; however, the intrinsic locality of convolution operations makes these limited effectively modeling long-range dependencies that are vital to capture global information lanes. Additionally, numerous result considerable computational cost for complexity. To overcome difficulties, we propose efficient method by combining CNN...
A mononuclear four-coordinate Co(II) complex with a [CoIIO4] core, namely, PPN[Li(MeOH)4][Co(L)2] (1) (PPN = bis(phosphoranediyl)iminium; H2L perfluoropinacol), has been studied by X-ray crystallography, magnetic characterization, and theoretical calculations. This presents severely distorted coordination geometry. The O–Co–O bite angle is 83.42°/83.65°, the dihedral twist between chelate planes 55.6°. structural distortion results in large easy-axis anisotropy D −104(1) cm–1 transverse...
A triple-bridged Cu(<sc>ii</sc>) chain compound with μ-1,1-(EO)azido, <italic>syn</italic>,<italic>syn</italic>-carboxylate, and μ2-ethanol linkers exhibits slow-relaxation long-range magnetic ordering.
Abstract Metallofullerenes of Gd x Ho 3− N@C 80 and Lu encapsulating mixed‐metal nitride clusters were synthesized. Spectroscopic characterization was employed to reveal their structural vibrational properties. The properties these species analyzed by using theoretical calculations. studies laid the foundations for be used as multifunctional molecules.
The solvent effect leads to structural transformation and tunable magnetism of chain-like azido-copper coordination polymers.
Two air-stable Co(III)-Co(II) mixed-valence complexes of molecular formulas [CoIICoIII(L)(DMAP)3(CH3COO)]·H2O·CH3OH (1) and [CoIICoIII(L)(4-Pyrrol)3 (CH3COO)]·0.5CH2Cl2 (2) (H4L = 1,3-bis-(5-methyl pyrazole-3-carboxamide) propane; DMAP 4-dimethylaminopyridine; 4-Pyrrol 4-pyrrolidinopyridine) were synthesized characterized by single-crystal X-ray crystallography, high-field electron paramagnetic resonance (HFEPR) spectroscopy, magnetic measurements. Both possess one five-coordinated Co(II)...
An air-stable trinuclear mixed-valence complex [CoIICoIII2L2(py)4]·2H2O (1) bearing a magnetic core [CoIIN4] has been synthesized using 1,3-bis(5-methylpyrazole-3-formylamine) propane (H4L) as ligand, which was investigated by single-crystal X-ray diffraction, measurements, and theoretical study. Due to the tetrahedral geometry of central Co(II) ion, this possesses negative large zero-field splitting D, exhibiting field-assisted slow relaxation magnetization with an effective energy barrier...
The structures and magnetic properties of three triple-bridged 1D azido–Cu(<sc>ii</sc>) coordination polymers are well-regulated by altering the coordinated alkanol molecules.
Precise control of the crystal field and local symmetry around paramagnetic spin center is crucial for design synthesis single-molecule magnets (SMMs). Herein, three mononuclear Dy(III)-based complexes, [Dy(L
Coligand effects lead to two mononuclear octahedral Co(<sc>ii</sc>) complexes exhibiting easy-axis magnetic anisotropies and distinct properties.