A5100358634- Metal-Organic Frameworks: Synthesis and Applications
- Medicinal Plant Pharmacodynamics Research
- Natural product bioactivities and synthesis
- Phytochemical compounds biological activities
- Synthesis and characterization of novel inorganic/organometallic compounds
- Electrochemical Analysis and Applications
- Organoboron and organosilicon chemistry
- Supercapacitor Materials and Fabrication
- Coordination Chemistry and Organometallics
- Organophosphorus compounds synthesis
- Nanomaterials for catalytic reactions
- Polymer composites and self-healing
- Chemical Reactions and Isotopes
- Organometallic Compounds Synthesis and Characterization
- Spectroscopy and Chemometric Analyses
- Supramolecular Chemistry and Complexes
- Ferrocene Chemistry and Applications
- X-ray Diffraction in Crystallography
- Adsorption and biosorption for pollutant removal
- Asymmetric Hydrogenation and Catalysis
- Chronic Lymphocytic Leukemia Research
- Aerogels and thermal insulation
- Analytical chemistry methods development
- Analytical Chemistry and Chromatography
- Biochemical and Molecular Research
Zunyi Medical University
2023-2024
Central South University of Forestry and Technology
2021-2024
Central South University
2021-2024
Ningbo University
2022-2023
University of Turku
2022
Lanzhou Institute of Chemical Physics
2020
Chinese Academy of Sciences
2020
Xi'an University of Science and Technology
2020
Southwest University of Science and Technology
2010
The germylene species (CH{(CMe)(2,6-iPr
The reaction of the stannyl phosphaketene (Nacnac)SnPCO 1 (Nacnac = CH{(CMe)(2,6-iPr2C6H3N)}2) with B(C6F5)3 produced 1,4-addition product (Nacnac)SnPCO(B(C6F5)3). However, corresponding reactions in presence dimethyl maleate, diisopropyl fumarate or diethyl-but-2-ynedioate gave [2+2] addition yielding four-membered phosphacycles, ((Nacnac)Sn(MeO2C))CHPC(OB(C6F5)3)CH(CO2Me), [(C6F5)3B)PC(OSn)C(CO2Me)CH(CO2Me)]2, (Nacnac)Sn(iPrO2C)CC(OAl(C6F5)3)P[CH(CO2iPr)CH2(CO2iPr)]CH(CO2iPr), and...
Abstract Glycosylation plays an important role in many biological processes, and its structural changes have a significant impact on activity. Unlike natural icariin, icariside I, II, simulated unnatural 5‐glycosylation ( 4 ) was designed to expand substrate adaptability the pharmacological properties of parent compound. Therefore, starting from commercially available icaritin, 5‐glycosylated icaritin successfully synthesized moderate yield through cyclization, selective 3‐alkylation,...
The reaction of the germylene chloride (NacNac)GeCl (1, NacNac = CH{(CMe)(2,6-iPr2C6H3N)}2), phenylacetylene, and B(C6F5)3 gives intermolecular frustrated Lewis pair (FLP) addition product 2. In this case, Ge(II) center acts as a base. contrast, analogous thiocyanate 3 reacts independently with to give cation salt [(NacNac)Ge][SCNB(C6F5)3] 4. Subsequent in presence alkynes, γ-C 4 act acidic basic center, respectively, affect affording products [(NacNac)Ge(RCCR')][SCNB(C6F5)3] 5 6. Compound...
A convenient method has been developed for the glycol-conjugation in 3-position of β-anhydroicaritine a reasonable yield. The structure 3-glycosylated derivatives was confirmed to be correct by 1H NMR, 13C NMR and HRMS spectrum. These compounds are less soluble than icaritin, but more icariside II CCl4. screening results showed that 12h, 12i 12j had higher cytotoxicity HepG2 MCF-7 at concentration 50 μM.
Hexagonal boron nitride (h-BN) has the similar structure as graphitic material.It excellent mechanical strength, wide band gap, high chemical oxidation resistance, good electrical insulation and outstanding thermal conductivity, attracted increasing attention of many researchers.However, nanoscale h-BN is difficult to disperse easy agglomerate in solution that greatly restricts its practical applications.h-BN based aerogels low density, strength conductivity can be used ultralight conductive...
The synergistic effects of ferric stearate, ferrocene and nickel N,N-dibuty dithiocarbamate (NiDBC) on photocatalysis were studied. Absorption intensities redox abilities these pholocatalyst compounds investigated by Diffuse Reflectance Spectroscopy (DRS) cyclic voltammetry. study indicated that adding Ferric stearate to either or NiDBC reduced the absorption intensity at range 400-550nm. Mixed with NiDBC, absorbance ranges both broadened from 200-550nm 200-700nm. results voltammetry ability...
Supramolecular polymers self-assembled by small molecules are a type of new material with adaptive and biocompatible properties. However, the mechanical property these materials is always weak, impeding their applications in practice. Here, we reported that coacervation can be used to explore robust stable bulk without compromise responsiveness. The liquid-liquid separation process could sequester concentrate solutes, which facilitated non-covalent association building blocks equipped...