A5085164470- Metal-Organic Frameworks: Synthesis and Applications
- Covalent Organic Framework Applications
- CO2 Reduction Techniques and Catalysts
- Polyoxometalates: Synthesis and Applications
- Carbon dioxide utilization in catalysis
- Catalysis and Oxidation Reactions
- Advanced Photocatalysis Techniques
- Magnetism in coordination complexes
- Carbon Dioxide Capture Technologies
- Catalysts for Methane Reforming
- Nanocluster Synthesis and Applications
- Advanced Nanomaterials in Catalysis
- Catalytic C–H Functionalization Methods
- Catalytic Cross-Coupling Reactions
Collège de France
2020-2022
Sorbonne Université
2020-2022
Université Paris Sciences et Lettres
2020-2022
Laboratoire de chimie des processus biologiques
2020-2022
Centre National de la Recherche Scientifique
2020-2022
Université de Versailles Saint-Quentin-en-Yvelines
2020-2022
Université Paris-Saclay
2020-2022
Institut Lavoisier de Versailles
2020-2022
The Keggin-type polyoxometalate (POM) PW12O403– and the catalytic complex Cp*Rh(bpydc)Cl2 (bpydc = 2,2′-bipyridine-5,5′-dicarboxylic acid) were coimmobilized in Zr(IV) based metal organic framework UiO-67. POM is encapsulated within cavities of MOF by situ synthesis, then, Rh introduced postsynthetic linker exchange. Infrared Raman spectroscopies, 31P 13C MAS NMR, N2 adsorption isotherms, X-ray diffraction indicate structural integrity all components (POM, Rh-complex MOF) composite interest...
Abstract The molecular‐level structuration of two full photosystems into conjugated porous organic polymers is reported. strategy heterogenization gives rise to which are still fully active after 4 days continuous illumination. Those materials catalyze the carbon dioxide photoreduction driven by visible light produce up three grams formate per gram catalyst. covalent tethering sites a single framework shown play key role in activation unprecedented long‐term efficiency arises from an optimal...
A complete picture of the reaction mechanism driving photocatalytic reduction CO 2 into formate promoted by Zr-based porphyrinic MOF-545 in CH 3 CN/TEOA solutions is provided for first time combining experimental and computational approaches.
Direct C–H functionalization catalyzed by a robust and recyclable heterogeneous catalyst is highly desirable for sustainable fine chemical synthesis. Bipyridine units covalently incorporated into the backbone of porous organic polymer were used as macroligand heterogenization molecular nickel catalyst. A controlled loading within achieved, coordination to bipyridine (bpy) sites assessed at level using IR solid-state NMR spectroscopy. The heterogenized Ni-bpy was successfully applied direct...
We report the templating effect of PW<sub>12</sub> polyoxometalate on porphyrinic MOF topologies whereby kinetic phase is favored at high temperature.
Abstract The molecular‐level structuration of two full photosystems into conjugated porous organic polymers is reported. strategy heterogenization gives rise to which are still fully active after 4 days continuous illumination. Those materials catalyze the carbon dioxide photoreduction driven by visible light produce up three grams formate per gram catalyst. covalent tethering sites a single framework shown play key role in activation unprecedented long‐term efficiency arises from an optimal...