A5051618537- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Energetic Materials and Combustion
- Thermal and Kinetic Analysis
- Crystallography and molecular interactions
- Combustion and Detonation Processes
- Chemical Thermodynamics and Molecular Structure
- Advanced Photocatalysis Techniques
- Rocket and propulsion systems research
- High-pressure geophysics and materials
- Boron and Carbon Nanomaterials Research
- Metal-Organic Frameworks: Synthesis and Applications
- Catalysts for Methane Reforming
- Luminescence Properties of Advanced Materials
- Covalent Organic Framework Applications
- Banking stability, regulation, efficiency
- Thermochemical Biomass Conversion Processes
- Microwave Dielectric Ceramics Synthesis
- Credit Risk and Financial Regulations
- Suicide and Self-Harm Studies
- Energy, Environment, Economic Growth
- Force Microscopy Techniques and Applications
- Concrete and Cement Materials Research
- Mechanical and Optical Resonators
- Molecular Communication and Nanonetworks
China Aerospace Science and Technology Corporation
2024-2025
Huashan Hospital
2025
Fudan University
2025
Huaqiao University
2024-2025
Shanghai Jiao Tong University
2025
Ministry of Agriculture and Rural Affairs
2024
Northwest A&F University
2023-2024
Central South University
2021-2024
Beijing Institute of Technology
2021-2024
Lanzhou University
2022-2024
After the tremendous advances over past two decades, micro-/nanorobots can effectively convert other forms of energy into propulsion and movement, as well be navigated to targeted locations under physiological conditions environments. They have been demonstrated potential load, transport, deliver therapeutic payloads directly disease sites, thereby improving efficacy reducing systemic side effects highly toxic drugs. In this feature article, various modalities ranging from...
The performance of energetic coordination compounds (ECCs) is influenced by their components and structure. Modifying the chemical structure ligands can balance detonation sensitivity. This study introduced Cu(3-PZCA)2(ClO4)2 (ECCs-1) Cu(2-IZCA)2(ClO4)2 (ECCs-2), using 3-PZCA 2-IZCA as ligands. ECCs-2, with a higher symmetry fewer nitrogen chains, showed highest thermal decomposition temperature (225 °C). Both ECCs displayed high mechanical sensitivity, ECCs-2 being slightly less sensitive...
An effective and novel design strategy for ultrafast laser-initiating materials has been established on the basis of coordination chemistry first time in present work. In view positive effect Ag ion perchlorate laser sensitivity, silver as a representative oxidizing inorganic metal salts was used to construct energetic cationic polymers (ECCPs), which solved inconvenient situation caused by difficulty applying these directly because unavoidable hygroscopicity inhomogeneity physical mixtures...
Heat-resistant explosives play an irreplaceable role in specialized applications. Two energetic metal-organic frameworks (EMOFs), potassium 4,4'-oxybis[3,3'-(5-tetrazol)]furazan and (1,2,4-triazol-3-yl)tetrazole, featuring a three-dimensional framework structure, were first synthesized characterized by chemical (1H NMR, 13C MS, IR spectroscopy, single-crystal XRD) physicochemical analyses (sensitivity toward friction, impact, electrostatic, DSC-TGA test). The new 3D EMOFs found to show high...
Nitro groups have been demonstrated to play a decisive role in the development of most powerful known energetic materials. Two trinitromethyl-substituted 1H-1,2,4-triazole bridging nitropyrazoles were first synthesized by straightforward routes and characterized chemical (MS, NMR, IR spectroscopy, single-crystal X-ray diffraction) experimental analysis (sensitivity toward friction, impact, differential scanning calorimetry-thermogravimetric test). Their detonation properties (detonation...
Alkali and alkaline-earth metal salts with 3,4-dinitropyrazole (DNP) were synthesized by the reaction of DNP stoichiometric amounts corresponding hydroxide-, oxide-, or carbonate-based highly pure salts, products fully characterized. Determination single-crystal structures all new complexes except for lithium strontium was performed X-ray diffraction techniques. The cesium salt crystallized no water among them. Differential scanning calorimetry (DSC) thermogravimetric analysis (TGA)...
A copper(II)-based quadridentate chelate [Cu(BNATE)·2H 2 O] has been prepared and systematically studied. It excellent near-infrared laser sensitivity detonation performance, low mechanical sensitivity.
An ingenious strategy based on energetic metal–organic frameworks with cesium salts for green and practical pyrotechnic composition has been described.
The high energy coordination compounds Cu(TZCA)2(ClO4)2 (ECCs-1) was prepared by 1H-tetrazole-5-carbohydrazide (TZCA) with a skeleton and strong ability group. At the same time, reaction activity of ligand explored, single crystal structure it intermediate were obtained. structures all substances characterized IR EA. And composition ECCs-1 are confirmed ESP, AC, SEM ICP-OES. Physical chemical properties tests show that has an acceptable thermal stability (Td = 177°C) extremely sensitive...
Using two routes, this study designed and synthesized a novel azo-linked four-heterocyclic compound, 1,2-bis(5-(1H-tetrazol-5-yl)-4H-1,2,4-triazol-3-yl) diazene (3, H4BTTD), with high yields. It corroborated that large conjugated planar energetic molecules in compounds, exemplified by H4BTTD, contribute to the formation of layered crystal stacking based on abundant hydrogen bonds interlayer π-π interactions. This markedly diminishes mechanical sensitivities compounds. Single-crystal X-ray...