A5012613474- Electrocatalysts for Energy Conversion
- Advanced Photocatalysis Techniques
- Catalytic Processes in Materials Science
- Advanced battery technologies research
- Copper-based nanomaterials and applications
- CO2 Reduction Techniques and Catalysts
- Fuel Cells and Related Materials
- Advancements in Battery Materials
- Advanced Battery Materials and Technologies
- Electronic and Structural Properties of Oxides
- Ammonia Synthesis and Nitrogen Reduction
- Electrochemical Analysis and Applications
- Supercapacitor Materials and Fabrication
- Machine Learning in Materials Science
- MXene and MAX Phase Materials
- Ionic liquids properties and applications
- Covalent Organic Framework Applications
- SARS-CoV-2 and COVID-19 Research
- Carbon dioxide utilization in catalysis
- Molecular Junctions and Nanostructures
- Catalysis and Hydrodesulfurization Studies
- Advanced Memory and Neural Computing
- Chalcogenide Semiconductor Thin Films
- Membrane-based Ion Separation Techniques
- Electrochemical sensors and biosensors
Chongqing University
2024-2025
Dalian Institute of Chemical Physics
2015-2024
Collaborative Innovation Center of Chemistry for Energy Materials
2016-2024
Chinese Academy of Sciences
2015-2024
University of Chinese Academy of Sciences
2016-2023
Xiamen University
2016-2021
Doping single-atom metals into MoS<sub>2</sub> matrix can efficiently trigger the electrocatalytic hydrogen evolution activity of inert S atoms on 2D surface and meanwhile enhance catalytic stability anti-poison ability.
Abstract The lack of highly efficient, inexpensive catalysts severely hinders large-scale application electrochemical hydrogen evolution reaction (HER) for producing hydrogen. MoS 2 as a low-cost candidate suffers from low catalytic performance. Herein, taking advantage its tri-layer structure, we report nanofoam catalyst co-confining selenium in surface and cobalt inner layer, exhibiting an ultra-high large-current-density HER activity surpassing all previously reported heteroatom-doped ....
The electrocatalytic decomposition of the abundant and toxic H<sub>2</sub>S from industrial by-products is a promising energy conversion technology for H<sub>2</sub> production simultaneously removing this environmental pollutant.
Perturbing the electronic structure of MoS2 basal plane by confining heteroatoms offers opportunity to trigger in-plane activity for hydrogen evolution reaction (HER). The key challenge consists inducing optimum HER controlling type and distribution confined atoms. A distance synergy -confined single-atom rhodium is presented, leading an ultra-high at S sites adjacent rhodium. By optimizing between Rh atoms, ultra-low overpotential 67 mV achieved a current density 10 mA cm-2 in acidic...
Abstract The electrocatalytic synthesis of C–N coupling compounds from CO 2 and nitrogenous species not only offers an effective avenue to achieve carbon neutrality reduce environmental pollution, but also establishes a route synthesize valuable chemicals, such as urea, amide, amine. This innovative approach expands the application range product categories beyond simple carbonaceous in reduction, which is becoming rapidly advancing field. review summarizes research progress urea synthesis,...
Nitrogen-doped (N-doped) carbon materials have been widely studied for electrocatalytic CO2R to CO. However, the active sites in N-doped remain under debate owing complication N types and challenge controllable synthesis. Here, via an innovative approach of template-assisted pyrolysis phthalocyanine, we achieve a controlled preparation foams. Electrochemical experiments show that catalyst dominated by graphitic rather than other drives highly selective CO against hydrogen evolution reaction,...
Abstract Achieving CO oxidation at room temperature is significant for gas purification but still challenging nowadays. Pt promoted by 3 d transition metals (TMs) a promising candidate this reaction, TMs are prone to be deeply oxidized in an oxygen-rich atmosphere, leading low activity. Herein we report unique structure design of graphene-isolated from CoNi nanoparticles (PtǀCoNi) efficiently catalytic atmosphere. alloy protected ultrathin graphene shell and therefore modulates the...
This work reports that via confining high density of 16 wt% single Mo atoms into the lattice CoOOH nanosheets and simultaneously fabricating robust nanoframes nanosheets, an unprecedented large-current-density OER activity is achieved.
Platinum is widely regarded as the most efficient catalyst for hydrogen evolution reaction (HER). However, overpotential increases, kinetics of HER significantly declines and mechanism exhibits potential-dependent behavior. Through a combination theoretical simulations experimental testing, we investigated changes in underlying kinetic reasons within control potential region. The results revealed that at low cathodic overpotential, follows Volmer–Tafel Pt(111)/water interface, while high it...
The development of anion exchange membranes (AEMs) capable facilitating rapid hydroxide ion transport, while maintaining robust mechanical stability, is considered a key direction for advancing hydrogen energy conversion systems. Herein, we synthesized series AEMs by grafting covalent organic frameworks (COFs) onto triphenylpiperidine copolymer and systematically evaluated the performance AEMs. tailored COFs, characterized an extensive bond network high micro‐porosity, created interconnected...
The reversible conversion reaction of a SEI was enabled by FeN X catalysts, which provided novel avenues for designing anode materials. Furthermore, large number spin-polarized electrons were stored in the already-reduced Fe species.
Abstract Despite tremendous importance in catalysis, the design of oxide-metal interface has been hampered by limited understanding nature interfacial sites and interaction (OMI). Through construction well-defined Cu 2 O/Pt, O/Ag O/Au interfaces, we find that O nanostructures (NSs) on Pt exhibit much lower thermal stability than Ag Au, although they show same structure. The activities these interfaces are compared for CO oxidation follow order O/Pt > O/Ag. OMI is found to determine...
Abstract Perturbing the electronic structure of MoS 2 basal plane by confining heteroatoms offers opportunity to trigger in‐plane activity for hydrogen evolution reaction (HER). The key challenge consists inducing optimum HER controlling type and distribution confined atoms. A distance synergy ‐confined single‐atom rhodium is presented, leading an ultra‐high at S sites adjacent rhodium. By optimizing between Rh atoms, ultra‐low overpotential 67 mV achieved a current density 10 mA cm −2 in...
The sluggish four-electron-transfer kinetics of the oxygen evolution reaction (OER) is a great challenge for development efficient and cost-effective OER electrocatalysts. Herein, we report single-atomic Ir Mo co-confined in lattice Co layered hydroxide (Co-LH) nanobox as an electrocatalyst via sacrificial template method. With hollow structure synergetic electronic interactions among Ir, Mo, Co-LH, catalyst delivers ultralow overpotential 220 mV at 10 mA cm–2 high durability over 800 h 50 1...
Decoupled electrolysis of water is a promising strategy for peak load regulation electricity. The key to developing this technology construct decoupled devices containing stable redox mediators and corresponding efficient catalysts, which remains considerable challenge. Herein, we designed high-performance device, using polysulfides as graphene-encapsulated CoNi catalysts. It produced H2 with low potential 0.82 V at 100 mA/cm2, saving 60.2% more energy than direct electrolysis. capacity...
The electrocatalytic oxidation of ethylene glycol (EG) to produce valuable glycolic acid (GLYA) is a promising strategy tackle EG overcapacity. Despite the good selectivity Pd for oxidation, its performance constrained by limited mass activity and toxicity intermediates like CO or CO-analogues. This study reports alloying with Ni Mo metals enhance durability in alkaline media. Notably, peak current density reached up 2423 mA mg-1, double that pristine Pd/C, accompanied GLYA Faraday...