A5094005079Novosibirsk State University
2024
Novosibirsk Institute of Organic Chemistry
2024
A wide range of organic molecules can participate in hydrogen atom transfer (HAT) processes as both HAT-donors and photo-HAT-acceptors simultaneously. Therefore, it opens the possibilities to exclude catalysts for C-H functionalization such cases. This is underlying idea presented catalyst-free bond fluorination approach. We demonstrated that broad aryl alkyl ketones be efficiently fluorinated with Selectfluor-based reagents at benzylic position under UV-A irradiation without any added...
A wide range of organic molecules can participate in hydrogen atom transfer (HAT) processes as both HAT-donors and photo-HAT-acceptors simultaneously. Therefore, it opens the possibilities to exclude catalysts for C-H functionalization such cases. This is underlying idea presented catalyst-free bond fluorination approach. We demonstrated that broad aryl alkyl ketones be efficiently fluorinated with Selectfluor-based reagents at benzylic position under UV-A irradiation without any added...