About
Contact & Profiles
A5074019054
Research Areas
- Synthetic Organic Chemistry Methods
- Fluorine in Organic Chemistry
- Organoboron and organosilicon chemistry
Enamine (Ukraine)
2020
An approach to the synthesis of oxa‐ and azabicyclo[ n .1.0]alkan‐1‐yl trifluoroborates on a multigram scale was developed. Two synthetic strategies were evaluated: first based lithiation–borylation corresponding 2‐bromoallyl derivatives, other relying regioselective hydroboration appropriate hetera‐substituted enynes. The second method appeared be more efficient in terms scalability substrate scope. Further steps included ring closing‐metathesis, mild palladium‐catalyzed cyclopropanation...
10.1002/ejoc.202000977
article
EN
European Journal of Organic Chemistry
2020-09-10
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