A5095708338- Magnetism in coordination complexes
- Magnetic and transport properties of perovskites and related materials
- Catalytic Processes in Materials Science
- Electrocatalysts for Energy Conversion
- Metal-Catalyzed Oxygenation Mechanisms
- N-Heterocyclic Carbenes in Organic and Inorganic Chemistry
- Metal complexes synthesis and properties
- Lanthanide and Transition Metal Complexes
- Crystal Structures and Properties
- Copper-based nanomaterials and applications
- Advanced Condensed Matter Physics
Friedrich Schiller University Jena
2024-2025
University of Bayreuth
2024
The switching phenomena of spin crossover (SCO) and valence tautomerism (VT) are respectively dominated by iron(ii) cobalt-dioxolene systems. To explore new possibilities for SCO or VT, the redox-active α-diimine ligand bis((phenyl)imino)acenaphthene (Ph-BIAN), which can adopt neutral (L0), monoanionic (L˙-), dianionic (L2-) states, was paired with zinc, cobalt, manganese iron to give [M(Ph-BIAN)3](BPh4)2 (M = Zn (1), Co (2), Mn (3), Fe (4)). Compounds 1, 2 3 a temperature invariant...
Two novel isostructural cyanide-bridged hexadecanuclear complexes with the general formula {[Fe(CN)
Ruddlesden–Popper (RP) compounds of the general formula (AX)(ABX3)n with their unique sequence perovskite-like (ABX3) and rock-salt-like units (AX) promise applications in diverse fields such as catalysis superconductivity. Fluorination RP oxides often leads to dramatic changes material properties, caused by differences atomic electronic structure. While current research focuses on fluorination n = 1 type (A2BO4), 3 oxyfluorides have remained elusive. We present synthesis first iron-based...
Spinel oxides are promising multifunctional electrocatalysts based on earth‐abundant elements. While NiFe 2 O 4 and CoFe have been widely studied for the oxygen evolution reaction (OER), CuFe has less investigated. Herein, cubic nanoparticles synthetic using a microwave‐assisted approach. The effect of post‐synthetic calcination particle morphology, crystal structure, inherent properties such as optical bandgap, magnetic moment, or degree inversion is influence treatment electrochemical...