A General and Special Catalyst for Suzuki–Miyaura Coupling Processes

• DOI: 10.1002/anie.201002404
• Publication Date: 2010-07-15T12:09:30Z
• Authors: Wenjun Tang; Andrew G. Capacci; Xudong Wei; Wenjie Li; Andre White; Nitinchandra D. P...; Jolaine Savoie; Joe J. Gao; Sonia Rodriguez; Bo Qu; Nizar Haddad; Bruce Z. Lu; Dhileepkumar Kris...; Nathan K. Yee; Chris H. Senanayake
• Keywords: Coupling reaction; Palladium catalyst

Biaryl monophosphorus ligands containing a 2,3-dihydrobenzo[d][1,3]oxaphosphole framework are highly effective for the palladium-catalyzed Suzuki–Miyaura cross-coupling reactions of wide range substrates. Ligand 1 has demonstrated excellent performance coupling extremely hindered arylboronic acids. Detailed facts importance to specialist readers published as "Supporting Information". Such documents peer-reviewed, but not copy-edited or typeset. They made available submitted by authors. Please note: The publisher is responsible content functionality any supporting information supplied Any queries (other than missing content) should be directed corresponding author article.