Enantioselective Palladium(II) Phosphate Catalyzed Three‐Component Reactions of Pyrrole, Diazoesters, and Imines

Pyrrole Carbenoid Stereocenter Component (thermodynamics)
DOI: 10.1002/anie.201306824 Publication Date: 2013-11-04T14:57:14Z
ABSTRACT
Reaction trio: The title reaction delivers CH functionalized pyrrole derivatives in moderate to good yields. This novel three-component provides both syn- and anti-pyrrole having two contiguous stereocenters with regio-, diastereo-, enantioselectivity. process represents the first highly enantioselective palladium-carbenoid-mediated reaction. As a service our authors readers, this journal supporting information supplied by authors. Such materials are peer reviewed may be re-organized for online delivery, but not copy-edited or typeset. Technical support issues arising from (other than missing files) should addressed Please note: publisher is responsible content functionality of any Any queries content) directed corresponding author article.
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