Gold‐Catalyzed Diastereoselective Cycloisomerization of Alkylidene‐Cyclopropane‐Bearing 1,6‐Diynes
Cyclopropanes
Molecular Structure
Stereoisomerism
01 natural sciences
Catalysis
0104 chemical sciences
Diynes
Cyclization
Alkynes
Gold
DOI:
10.1002/anie.201405147
Publication Date:
2014-06-11T16:19:31Z
AUTHORS (4)
ABSTRACT
AbstractAn unprecedented gold‐catalyzed diastereoselective cycloisomerization of 1,6‐diynes bearing an alkylidene cyclopropane moiety has been developed. This methodology enables rapid access to a variety of 1,2‐trimethylenenorbornanes, which are important building blocks in the preparations of abiotic and sesquiterpene core structures.
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