Solid State Machinery of Multiple Dynamic Elements in a Metal–Organic Framework

• DOI: 10.1002/anie.202317094
• Publication Date: 2024-01-18T16:45:25Z
• Authors: Jacopo Perego; Andrea Daolio; Charl X. Bezuiden...; Sergio Piva; Giacomo Prando; Benjamin Costarella; Pietro Carretta; Luciano Marchiò; Dominik Kubicki; Piero Sozzani; Silvia Bracco; Angiolina Comotti
• Keywords: Crystal Engineering, Metal-Organic Frameworks, Molecular Dynamics, Molecular Rotor, Solid State NMR;; Crystal Engineering; Settore CHEM-03/A - Chimica generale e inorganica; Molecular Rotor; Molecular Dynamic; 500; Settore CHEM-05/A - Chimica organica; 540; Solid State NMR; Metal-Organic Framework; Crystal Engineering; Metal-Organic Frameworks; Molecular Dynamics; Molecular Rotor; Solid State NMR

Engineering coordinated rotational motion in porous architectures enables the fabrication of molecular machines solids. A flexible two-fold interpenetrated pillared Metal-Organic Framework precisely organizes fast mobile elements such as bicyclopentane (BCP) (10