Synthesis, crystal structure and properties of a new lanthanide‐transition metal carbonyl cluster

• DOI: 10.1002/aoc.1476
• Publication Date: 2008-12-24T16:49:38Z
• Authors: Jiehui Ye; Haiquan Su; Fenghua Bai; Yong Du; Yulong Zhang
• Keywords: Metal carbonyl; Thermogravimetric analysis; Carbonylation

Abstract A new type heterobimetallic complex containing lanthanide and transition metal carbonyl cluster (LnM cluster), Sm 2 {OOCCCo 3 (CO) 9 } {OOCCF 4 {(CO) Co CCOOH} , has been synthesized by reaction of CCOOH with Sm(OOCCF ) (H O) structurally characterized single‐crystal X‐ray diffraction. Application the as a catalyst precursor for hydrogenation carbon monoxide (Fischer–Tropsch reaction) was explored, thermogravimetric behavior magnetic properties compound were examined well. Copyright © 2008 John Wiley & Sons, Ltd.