ChemInform Abstract: An Enantioselective Total Synthesis and Stereochemical Revision of (+)‐Citrinadin B.
Stereoisomerism
Organic Chemicals
01 natural sciences
Indole Alkaloids
Substrate Specificity
0104 chemical sciences
DOI:
10.1002/chin.201402204
Publication Date:
2013-12-20T17:59:55Z
AUTHORS (7)
ABSTRACT
This manuscript describes an enantioselective synthesis of the naturally occurring alkaloid citrinadin B. The synthetic effort revealed an anomaly in the original structural assignment that has led to the proposal of a stereochemical revision. This revision is consistent with the structures previously reported for a closely related family of alkaloids, PF1270A-C. The synthesis is convergent and employs a stereoselective intermolecular nitrone cyloaddition reaction as a key step.
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