Reactive Polymer Coatings: A General Route to Thiol‐ene and Thiol‐yne Click Reactions
Polymers
Surface Properties
Quinolinium Compounds
Fibrinogen
02 engineering and technology
Alkenes
Polymerization
Alkynes
Click Chemistry
Amino Acid Sequence
Gases
Sulfhydryl Compounds
0210 nano-technology
DOI:
10.1002/marc.201200011
Publication Date:
2012-02-20T19:26:25Z
AUTHORS (6)
ABSTRACT
AbstractReactive polymer coatings were synthesized via chemical vapor deposition (CVD) polymerization process. These coatings decouple surface design from bulk properties of underlying materials and provide a facile and general route to support thiol‐ene and thiol‐yne reactions on a variety of substrate materials. Through the reported technique, surface functions can be activated through a simple design of thiol‐terminated molecules such as polyethylene glycols (PEGs) or peptides (GRGDYC), and the according biological functions were demonstrated in controlled and low‐fouling protein adsorptions as well as accurately manipulated cell attachments.
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