Efficient Access to 3D Mesoscopic Prisms in Polymeric Soft Materials

• DOI: 10.1002/marc.202100064
• Publication Date: 2021-03-16T07:00:11Z
• Authors: Xiaolin Lyu; Hanlin Huang; Zhehao Tang; Longfei Luo; Wenjun Luo; Yan Yu; Zhihao Shen; Xing‐He Fan; Zhigang Zou
• Keywords: Mesoscopic physics; Soft materials

Abstract The preparation of 3D functional isolated mesoscopic assemblies remains a challenge in the self‐assembly polymers. Here, well‐defined hexagonal and hexagram prisms with uniform dimensions are acquired by crystallization inclusion complex composed crystalline molecule tris‐ o ‐phenylenedioxycyclotriphosphazene (TPP) block copolymer. TPP plays an important role self‐assembling process. faceted morphologies infrequent field soft materials. formation experiences growth mechanism. epitaxial growth, accompanied heterogeneous nucleation edges, yields crystals. This study provides path to construct polymeric materials broad utility based on numerous supramolecular complexes.