Optimizing the lignin based synthesis of flexible polyurethane foams employing reactive liquefying agents

• DOI: 10.1002/pi.4905
• Publication Date: 2015-03-02T05:35:26Z
• Authors: Jacopo Bernardini; Irene Anguillesi; Maria-Beatrice Co...; Patrizia Cinelli; Andrea Lazzeri
• Keywords: Flexible foam; Green chemistry; Lignin; Microwave; Polyurethane; Renewable sources; Polymers and Plastics; microwave; polyurethane; green chemistry; 13. Climate action; 8. Economic growth; lignin; 02 engineering and technology; renewable sources; 0210 nano-technology; 7. Clean energy; flexible foam; 12. Responsible consumption

The present work is focused on the optimization of a green process based on the employment of by-products obtained from wood treatments as raw materials for producing flexible polyurethane foams. More specifically, lignin was employed in flexible polyurethane foams in order to partially replace the usual fossil polyols; therefore glycerol (GLY) and glycerin polyglycidyl ether (EJ 300) were used as the polyol fraction for lignin liquefaction. Polypropylene glycol triol was used as a chain extender in different ratios with liquefaction solvents, and polymeric diphenylmethane diisocyanate as an isocyanate fraction. Liquefaction of lignin was performed by microwave irradiation, thus reducing the processing time and energy required compared to present industrial production processes. All the foams were produced in controlled expansion through the adoption of a ‘one-shot’ approach, using water as a blowing agent and with an isocyanate index (NCO/OH) of less than 100 to improve the flexibility of the foam. This approach allowed for the substitution of up to 12% of common petro derived polyol with commercial soda lignin. Finally, the foams were characterized, presenting properties that could be modulated as a function of lignin content, GLY/EJ 300 ratio and isocyanate index. The qualities of the foams were compatible with existing materials used for furniture and for the interiors of car seats and couches. © 2015 Society of Chemical Industry