Effect of Sn on methane decomposition over Fe supported catalysts to produce carbon
Carbon fibers
Deposition
DOI:
10.1007/s10751-011-0348-y
Publication Date:
2011-08-24T09:23:42Z
AUTHORS (6)
ABSTRACT
In this work, alumina-supported Sn containing Fe catalysts were investigated in CVD reactions (Chemical Vapor Deposition) using methane for carbon production. The catalysts were prepared with 10 wt.% of Fe (as Fe2O3) and 3, 6 and 12 wt.% of Sn (as SnO2) supported on Al2O3 named hereon Fe10Sn3A, Fe5Sn6A and Fe10Sn12A, respectively. These catalysts were characterized by SEM, TPCVD, TPR, TG, Raman, XRD and 57Fe and 119Sn Mossbauer spectroscopy. Methane reacts with Fe10A catalyst (without Sn) in the temperature range 680–900°C to produce mainly Fe0, Fe3C and 20 wt.% of carbon deposition. TPR and TPCVD clearly showed that Sn strongly hinders the CH4 reaction over Fe catalyst. 57Fe Mossbauer suggested that in the presence of Sn the reduction of Fe + 3 by methane becomes very difficult. 119Sn Mossbauer showed Sn + 4 species strongly interact with metallic iron after CVD, producing iron-tin phases such as Fe3SnC and FeSn2. This interaction Sn–Fe increases the CVD temperatures and decreases the carbon yield leading to the production of more organized forms of carbon such as carbon nanotubes, nanofibers and graphite.
SUPPLEMENTAL MATERIAL
Coming soon ....
REFERENCES (11)
CITATIONS (1)
EXTERNAL LINKS
PlumX Metrics
RECOMMENDATIONS
FAIR ASSESSMENT
Coming soon ....
JUPYTER LAB
Coming soon ....