Critical assessment of a TiO2-Ag-ZnO nanocomposite photocatalyst on improved photocatalytic activity under mixed UV-visible light

Photocatalyst Plasmonic 01 natural sciences TP250-261 0104 chemical sciences Industrial electrochemistry Z-scheme ZnO TA401-492 TiO2 Ag NPs Materials of engineering and construction. Mechanics of materials
DOI: 10.1016/j.apsadv.2023.100500 Publication Date: 2023-11-19T16:03:53Z
ABSTRACT
In recent years, semiconductor photocatalysts such as zinc oxide (ZnO) and titanium dioxide (TiO2) have been studied to utilize solar light for energy production and environmental remediation. However, their wide band gap energy and fast charge recombination limit their practical applications. So far, various approaches, such as noble metal incorporation, metal oxide coupling, and the design of Z-scheme photocatalyst systems, among others, have been explored to enhance the lifetime of photogenerated charge carriers in ZnO and TiO2. In this study, a novel TiO2-Ag-ZnO nanocomposite photocatalyst has been successfully synthesized by a combination of wet chemistry, photochemistry, and plasma-based processes. Simple spin coating of ZnO thin films was coupled with subsequent photodeposition of metallic Ag nanoparticles (NPs). Afterward, well-uniform TiO2 NPs (roughly 18 nm) were deposited on this unique Ag-ZnO surface via a gas cluster aggregation source (GAS) process. The results showed that the activity of the ZnO photocatalyst under mixed UV-visible light was significantly increased by the TiO2 and Ag contributions. A single mechanism to be responsible for the photocatalytic activity can be excluded. Instead, a critical assessment of the possible mechanisms corresponding to the different interfaces present at the TiO2-Ag-ZnO surface including a Z–scheme is provided.
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