Critical assessment of a TiO2-Ag-ZnO nanocomposite photocatalyst on improved photocatalytic activity under mixed UV-visible light
Photocatalyst
Plasmonic
01 natural sciences
TP250-261
0104 chemical sciences
Industrial electrochemistry
Z-scheme
ZnO
TA401-492
TiO2
Ag NPs
Materials of engineering and construction. Mechanics of materials
DOI:
10.1016/j.apsadv.2023.100500
Publication Date:
2023-11-19T16:03:53Z
AUTHORS (12)
ABSTRACT
In recent years, semiconductor photocatalysts such as zinc oxide (ZnO) and titanium dioxide (TiO2) have been studied to utilize solar light for energy production and environmental remediation. However, their wide band gap energy and fast charge recombination limit their practical applications. So far, various approaches, such as noble metal incorporation, metal oxide coupling, and the design of Z-scheme photocatalyst systems, among others, have been explored to enhance the lifetime of photogenerated charge carriers in ZnO and TiO2. In this study, a novel TiO2-Ag-ZnO nanocomposite photocatalyst has been successfully synthesized by a combination of wet chemistry, photochemistry, and plasma-based processes. Simple spin coating of ZnO thin films was coupled with subsequent photodeposition of metallic Ag nanoparticles (NPs). Afterward, well-uniform TiO2 NPs (roughly 18 nm) were deposited on this unique Ag-ZnO surface via a gas cluster aggregation source (GAS) process. The results showed that the activity of the ZnO photocatalyst under mixed UV-visible light was significantly increased by the TiO2 and Ag contributions. A single mechanism to be responsible for the photocatalytic activity can be excluded. Instead, a critical assessment of the possible mechanisms corresponding to the different interfaces present at the TiO2-Ag-ZnO surface including a Z–scheme is provided.
SUPPLEMENTAL MATERIAL
Coming soon ....
REFERENCES (50)
CITATIONS (6)
EXTERNAL LINKS
PlumX Metrics
RECOMMENDATIONS
FAIR ASSESSMENT
Coming soon ....
JUPYTER LAB
Coming soon ....