Electrochemical performances of LiNi1−xMnxPO4 (x = 0.05–0.2) olivine cathode materials for high voltage rechargeable lithium ion batteries

• DOI: 10.1016/j.apsusc.2017.12.060
• Publication Date: 2017-12-12T23:45:58Z
• Authors: S. Karthikprabhu; K. Karuppasamy; Dhanasekaran Vikr...; K. Prasanna; T. Maiyalagan; A. Nichelson; A. Kathalingam; Hyun-Seok Kim
• Keywords: Lithium iron phosphate

Abstract This study demonstrated to synthesis of carbon-free lithium nickel phosphate (LiNiPO4) and its analogue of manganese doped LiNi1−xMnxPO4 (x = 0.05–0.2) cathode materials by a facile polyol method and their suitability for use in high voltage lithium ion batteries (LIBs). The physicochemical properties were analyzed using X-ray diffraction, Fourier transform infra-red, Raman, field emission scanning electron microscopy (FE-SEM), energy dispersive analysis by X-ray (EDX), and electrochemical studies. FE-SEM showed that the spherical shape particles were uniformly distributed on the surface and EDX confirmed the presence of all the elements in the LiNi1−xMnxPO4 nanostructure. Substitution of Mn dopants with LiNiPO4 significantly improved the electrical and electrochemical performances for LiNi1−xMnxPO4 (x = 0.05–0.2) cathodes. The highly conducting LiNi1−xMnxPO4 (x = 0.1) cathode exhibited initial discharge capacity of 94.2 mA h g−1 at C/4 rate, and 62% capacity retention after 100 cycles between 2.8 and 5.6 V. These features promote LiNi1−xMnxPO4 as a suitable cathode material for high voltage LIBs.