Novel process for the coproduction of xylo-oligosaccharides, fermentable sugars, and lignosulfonates from hardwood

• DOI: 10.1016/j.biortech.2016.08.051
• Publication Date: 2016-08-13T07:29:37Z
• Authors: Caoxing Huang; Ben Jeuck; Jing Du; Qiang Yong; Hou-min Chang; Hasan Jameel; Richard Phillips
• Keywords: Glucose; Liquidambar; Hydrolysis; Carbohydrates; Oligosaccharides; Recycling; Lignin; Wood; 01 natural sciences; 0105 earth and related environmental sciences

Many biorefineries have not been commercialized due to poor economic returns from final products. In this work, a novel process has been developed to coproduce valuable sugars, xylo-oligosaccharides, and lignosulfonates from hardwood. The modified process includes a mild autohydrolysis pretreatment, which enables for the recovery of the xylo-oligosaccharides in auto-hydrolysate. Following enzymatic hydrolysis, the residue is sulfomethylated to produce lignosulfonates. Recycling the sulfomethylation residues increased both the glucan recovery and lignosulfonate production. The glucose recovery was increased from 81.7% to 87.9%. Steady state simulation using 100g of hardwood produced 46.7g sugars, 5.9g xylo-oligosaccharides, and 25.7g lignosulfonates, which were significantly higher than that produced from the no-recycling process with 39.1g sugars, 5.9g xylo-oligosaccharides, and 15.0g lignosulfonates. The results indicate that this novel biorefinery process can improve the production of fermentable sugars and lignosulfonate from hardwood as compared to a conventional biorefinery process.