Low-temperature reverse water gas-shift reaction over highly efficient Cu-hydrotalcites: Mechanistic insights on the role of malachite phase

• DOI: 10.1016/j.cattod.2023.114235
• Publication Date: 2023-05-24T15:39:57Z
• Authors: Débora Álvarez-He...; María Marín-Sánchez; Laura Lobo-Andrades; Lola Azancot; Luis F. Bobadilla; Svetlana Ivanova; Miguel A. Centeno
• Keywords: Water-gas shift reaction; Hydrotalcite; Malachite; Malachite green

Peer reviewed<br/>Carbon dioxide (CO2) transformation into valuable fuels and chemicals is in most cases a challenge far from readiness nowadays. One possible route for its conversion is the reverse water gas shift reaction (rWGS), crucial for syngas generation and required for the chemical conversion of CO2 to fuels and platform chemicals. In this paper, well organized Cu/Zn/Al structures were proposed as efficient catalysts for rWGS reaction at low temperatures. The results of in situ XRD revealed the formation of layered structures such malachite and hydrotalcite. The operando DRIFTS-MS studies of those structure suggests a participation of Cu2+/Cu+ pair in the reaction, promoting the redox mechanism and enhancing the activity at lower temperature. This work also provides a new strategy to design Cu-based rWGS catalysts able to prevent the sintering of active phase.<br/>Financial support for this work was obtained from Junta de Andalucia via Consejeria de Transformacion Economica, Industria, Conocimiento y Universidades (grant US-1263288) co-financed by FEDER funds from the European Union.<br/>