Corrosion inhibition of zinc by calcium exchanged beidellite clay mineral: A new smart corrosion inhibitor

• DOI: 10.1016/j.corsci.2013.10.037
• Publication Date: 2013-11-10T09:51:49Z
• Authors: A. Aït Aghzzaf; B. Rhouta; E. Rocca; A. Khalil; J. Steinmetz
• Keywords: 2. Zero hunger; 02 engineering and technology; 0210 nano-technology; 01 natural sciences; 0104 chemical sciences

Abstract The corrosion inhibition performances of zinc immersed in 0.1 M NaCl solution with and without CaCl2, Na+ and Ca2+ exchanged beidellite (BDT) clay mineral picked up from Agadir bassin (Morocco) was studiedby potentiodynamic measurements and electrochemical impedance spectroscopy. The chemical and microanalysis of Na+-BDT and Ca2+-BDT by different techniques reveal basal distances of clays, of about 1.22 and 1.48 nm respectively, consistent with the saturation of beidellite interlayer spaces with Na+ and Ca2+ ions surrounded by one and two equivalent layers of water respectively. EIS results and surface analysis show that Ca2+-BDT acts as a smart inhibitor on zinc surface by modifying the physicochemical parameters of electrolyte near the surface. The exchange reaction in BDT involves the concentration decrease or the “suppression” of Na+, CO 3 2 - and Cl− ions near the zinc surface.