Graphitic carbon nitride nanosheets doped graphene oxide for electrochemical simultaneous determination of ascorbic acid, dopamine and uric acid

• DOI: 10.1016/j.electacta.2014.07.094
• Publication Date: 2014-08-04T05:30:23Z
• Authors: Hanqiang Zhang; Qitong Huang; Yihong Huang; Feiming Li; Wuxiang Zhang; Chan Wei; Jianhua Chen; Pingwang Dai; Lizhang Huang; Zhouyi Huang; Lianping Kang; Shirong Hu; Aiyou Hao
• Keywords: Graphitic carbon nitride; Differential pulse voltammetry; Graphite oxide; Carbon nitride; Nanosheet; Carbon fibers

Abstract Graphitic carbon nitride nanosheets with a graphite-like structure have strong covalent bonds between carbon and nitride atoms, and nitrogen atoms in the carbon architecture can accelerate the electron transfer and enhance electrical properties effectually. The graphitic carbon nitride nanosheets-graphene oxide composite was synthesized. And the electrochemical performance of the composite was investigated by cyclic voltammetry and differential pulse voltammetry ulteriorly. Due to the synergistic effects of layer-by-layer structures by π-π stacking or charge-transfer interactions, graphitic carbon nitride nanosheets-graphene oxide composite can improved conductivity, electro-catalytic and selective oxidation performance. The proposed graphitic carbon nitride nanosheets-graphene oxide composite modified electrode was employed for simultaneous determination of ascorbic acid, dopamine and uric acid in their mixture solution, it exhibited distinguished sensitivity, wide linear range and low detection limit. Moreover, the modified electrode was applied to detect urine and dopamine injection sample, and then the samples were spiked with certain concentration of three substances with satisfactory recovery results.