Porous carbon derived from Metal–organic framework (MOF) for capacitive deionization electrode

• DOI: 10.1016/j.electacta.2015.07.130
• Publication Date: 2015-07-26T14:51:05Z
• Authors: Limin Chang; Jiarun Li; Xiaoyue Duan; Wei Liu
• Keywords: 01 natural sciences; 7. Clean energy; 0104 chemical sciences

Abstract Porous carbon (PC) was easily prepared by synthesis of a metal–organic framework (MOF-5) followed by carbonization step. The morphology, structure, Brunauer-Emmett-Teller (BET) surface areas, wettability, and electrochemical performance for PCs carbonized at different temperatures from 500 to 1000 °C were characterized by the techniques of scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier Transform Infrared Spectroscopy (FTIR), N2 adsorption-desorption, contact angle of glycerin, cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS), and compared with a commercially available activated carbon (AC). The results showed that MOF-5 was fully carbonated at 900 °C, having the highest specific surface area of 1563.09 m2 g−1 and the largest pore volume of 1.07 cm3 g−1. The PC carbonized at 900 °C (PC-900) exhibited better wettability, a higher specific capacity and a lower charge transfer resistance than other PCs and AC. In further capacitive deionization (CDI) process, the PC-900 electrode exhibited 9.39 mg g−1 CDI capacity, significantly higher than 5.47 mg g−1 of AC electrode. More importantly, easy and good repeatability could be obtained for PC-900 electrode. This study suggests that the PC-900 derived from MOF-5 may be a potential electrode material for CDI.